Nitrated cross-linked b-cyclodextrin binders exhibiting low glass transition tempratures

Polymeric binders such as β‐cyclodextrins (βCDs) are used to bind with other constituents of energetic formulations and to prevent accidental ignition. One of the advantages of βCDs is the ability to tune their properties by chemical modification. Here, we synthesised nitrated cross‐linked βCDs (βNCXCDs) to produce new binders for energetic formulations. The cross‐linking of βCD with non‐toxic triethylene glycol diglycidyl ether (TEGDGE, X=T) and poly(ethylene glycol) diglycidyl ethers (PEGDGE, X=P) yielded soft, water soluble oligomeric compounds (βCXCDs) which can improve the processability of energetic formulations and contribute to their desensitisation. When the PEGDGE cross‐linker was used, lower glass transition temperatures were achieved, which extended the operative range of the βCPCD binder to −20 °C. The analogous nitrated systems (βNCXCDs) were therefore synthesised using a 1 : 1 (v/v) ratio of 98 % sulfuric acid/100 % nitric acid or 100 % fuming nitric acid, increasing their solubility in acetone and tetrahydrofuran. The nitrated derivatives were characterised by decomposition temperatures (200 °C) and energies (up to 1750 J g−1) comparable to nitrocellulose. Moreover, the glass transition of the inert βCXCDs at low temperatures (<0 °C) was conserved in the corresponding nitrated βNCXCDs, ensuring the desensitisation of energetic compositions even at low temperatures. This is the first time that nitrated derivatives of βCD with glass transition temperatures below 0 °C have been reported, suggesting such derivatives could make suitable replacements for nitrocellulose and other binders in energetic formulations.