Cobalt doped JUC-160 derived functional carbon superstructures with synergetic catalyst effect for Li-SeS2 batteries
dc.contributor.author | Jin, Wen-Wu | |
dc.contributor.author | Li, He-Jun | |
dc.contributor.author | Zou, Ji-Zhao | |
dc.contributor.author | Zhang, Qi | |
dc.contributor.author | Inguva, Saikumar | |
dc.contributor.author | Zeng, Shao-Zhong | |
dc.contributor.author | Xu, Guo-Zhong | |
dc.contributor.author | Zeng, Xie-Rong | |
dc.date.accessioned | 2020-10-07T11:19:14Z | |
dc.date.available | 2020-10-07T11:19:14Z | |
dc.date.issued | 2020-07-03 | |
dc.description.abstract | The carbon nanostructures with polar metal/heteroatom co-doping are considered as an effective strategy to improve their electrochemical performances. In this context, the crystal-shape engineering is carried out. Based on a new ‘‘one for six’’ strategy, the JUC-160 having a two-dimensional (2D) zeolitic imidazolate framework is transformed into six different carbon materials. These materials do not need a carbon activation process or template removal process. Instead, after a simple carbonization, a series of metal/heteroatom co-doped carbon materials with novel structures are formed. To be highlighted, this work is the first report of using self-assembled carbon nanostructures/SeS2 composites as cathode materials in the field of Li-SeS2. Moreover, those carbon nanostructures can be effectively tailored by adjusting the method of cobalt doping and the amount of cobalt dopant. Because of the benefits from the novel structures and cobalt/nitrogen co-doping, the dissolution of poly-sulfides/selenides is reduced and a high content of SeS2 (73 wt%) is achieved. The optimized cathode displays an extraordinary cycle performance with a reversible capacity of 820.87 mA h g−1 after 100 cycles, and with reversible charge-discharge efficiency is close to 100% | en_UK |
dc.identifier.citation | Jin W-w, Li H-J, Zou J-z, et al., (2020) Cobalt doped JUC-160 derived functional carbon superstructures with synergetic catalyst effect for Li-SeS2 batteries. Microporous and Mesoporous Materials, Volume 306, October 2020, Article number 110438 | en_UK |
dc.identifier.issn | 1387-1811 | |
dc.identifier.uri | https://doi.org/10.1016/j.micromeso.2020.110438 | |
dc.identifier.uri | https://dspace.lib.cranfield.ac.uk/handle/1826/15865 | |
dc.language.iso | en | en_UK |
dc.publisher | Elsevier | en_UK |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Li-SeS2 | en_UK |
dc.subject | Crystal-shape engineering | en_UK |
dc.subject | Self-assembled | en_UK |
dc.subject | ZIF | en_UK |
dc.subject | Cobalt-doped | en_UK |
dc.title | Cobalt doped JUC-160 derived functional carbon superstructures with synergetic catalyst effect for Li-SeS2 batteries | en_UK |
dc.type | Article | en_UK |
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