Superior rate capability of high mass loading supercapacitors fabricated with carbon recovered from methane cracking

dc.contributor.authorBaptista, Joana
dc.contributor.authorShacklock, Jack
dc.contributor.authorShaban, Muhammad
dc.contributor.authorAlkayal, Anas
dc.contributor.authorLobato, Killian
dc.contributor.authorWijayantha, Upul K. G.
dc.date.accessioned2023-08-08T11:37:09Z
dc.date.available2023-08-08T11:37:09Z
dc.date.issued2023-07-27
dc.description.abstractHigh mass loading (ca. 30 mg/cm2) electrodes were prepared with carbon recovered from catalytic methane cracking (MC). As-fabricated supercapacitors displayed 74% of capacitance retention from 6 mA/cm2 to 60 mA/cm2 and a Ragone plot’s slope of −7 Wh/kW (compared to 42% and −31 Wh/kW, respectively, for high mass loading devices fabricated with commercial carbon). The high-rate capability of the MC-recovered carbon is attributed to the presence of carbon black and carbon nanotubes produced during the reaction, which likely increased the electronic and ionic conductivity within the electrode. These results suggest that the by-product of this hydrogen generation route might be a suitable active material for supercapacitors.en_UK
dc.description.sponsorshipEngineering and Physical Sciences Research Council (EPSRC): EP/R023662/1; EP/S023909/1en_UK
dc.identifier.citationBaptista J, Shacklock J, Shaban M, et al., (2023) Superior rate capability of high mass loading supercapacitors fabricated with carbon recovered from methane cracking, Inorganics, Volume 11, Issue 8, July 2023, Article Number 316en_UK
dc.identifier.issn2304-6740
dc.identifier.urihttps://doi.org/10.3390/inorganics11080316
dc.identifier.urihttps://dspace.lib.cranfield.ac.uk/handle/1826/20061
dc.language.isoenen_UK
dc.publisherMDPIen_UK
dc.rightsAttribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectsupercapacitorsen_UK
dc.subjectcarbon nanotubesen_UK
dc.subjectporous nanocarbon-based electrodesen_UK
dc.subjectmethane crackingen_UK
dc.subjectrate capabilityen_UK
dc.subjectelectrochemistryen_UK
dc.subjectelectrochemical impedance spectroscopyen_UK
dc.titleSuperior rate capability of high mass loading supercapacitors fabricated with carbon recovered from methane crackingen_UK
dc.typeArticleen_UK

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