Non-isothermal cure kinetics of aerogel/epoxy composites using differential scanning calorimetry
Date published
2019-02-11
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Journal Title
Journal ISSN
Volume Title
Publisher
Taylor and Francis
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Type
Article
ISSN
0360-2559
Format
Citation
Krishnaswamy S, Marchante V, Abhyankar H, et al., (2019) Non-isothermal cure kinetics of aerogel/epoxy composites using differential scanning calorimetry. Polymer-Plastics Technology and Engineering, Volume 58, Issue 16, 2019, pp. 1757-1765
Abstract
The present work determines the non-isothermal cure parameters of aerogel/epoxy samples along with the effect of a wetting agent. The cure parameters were calculated using Kissinger and isoconversional methods after which the reaction was modeled with the Sestak–Berggren equation. It is seen that the composites had higher activation energy and frequency factor values compared to the pure resin, and similarities in cure parameters between the aerogel/epoxy composites with and without the wetting agent were seen. Hence, the former’s use is advocated due to its positive influence on the resin–aerogel interface without sacrificing the cure parameters.
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Github
Keywords
aerogel, epoxy, cure kinetics, DSC, activation energy
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Attribution-NonCommercial 4.0 International