Kinetic simulation of a 100kWth oxy-combustor using Aspen Plus

Oxy-fuel combustion is a clean coal technology based on firing fuel in an enriched oxygen atmosphere to obtain high CO2 concentrations in the exhaust gas. Experimental tests were performed at Cranfield University using a 100kWth retrofitted oxy-combustor. In parallel, a kinetic simulation model using Aspen Plus was designed and validated to serve as a computer tool to predict the behaviour of the oxy-combustion process for a wide range of fuels and conditions. The main input parameters varied in the simulation study were: fuel type (El Cerrejon coal, Daw Millcoal, Cereal Co-product biomass, and coal/biomass blends); percentage of recycled flue gas (55, 60,and 65%); type of recycled flue gas (wet or dry); percentage of excess oxygen (0 and 5%), and the amount of air ingress into the process (0, 2, 10, and 18% of the total flue gas fed to the oxycombustor).The last input condition, percentage of air ingress, is of greater importance as a result of the unit being a retrofitted oxy-combustor; for which air ingress is more probable and this represents a situation likely to be an issue for any boiler retrofitted for oxyfuel firing. Results from the simulations as well as the definition of the operating conditions that best represents the behaviour of the rig are presented.