Influence of particle size and organic carbon content on distribution and fate of aliphatic and aromatic hydrocarbon fractions in chalks

Simple item page
dc.contributor.authorCao, Xingtao
dc.contributor.authorTemple, Tracey J.
dc.contributor.authorLi, Xingang
dc.contributor.authorCoulon, Frederic
dc.contributor.authorSui, Hong
dc.date.accessioned2021-02-18T15:57:04Z
dc.date.available2021-02-18T15:57:04Z
dc.date.issued2015-09-06
dc.description.abstractAlthough great efforts had been devoted to investigate the fate and transport of various hydrocarbon sources in major aquifers, there is still a need to better understand and predict their behaviour for robust risk assessment. In this study, the fate and distribution of the aliphatic and polycyclic aromatic hydrocarbons (PAHs) of diesel fuel in chalk aquifer was investigated using a series of leaching column tests and then modelled using the Contaminant Transport module of the Goldsim software. Specifically the influence of chalk particle size on the behaviour and fate of the hydrocarbons was investigated. Distribution coefficient () between the water and chalk solid phase according to chalk particle sizes was determined for each hydrocarbon group. The larger sizes of chalk particles have higher values. After 60 d of leaching using a water flow of 45 mm d−1, most of the aliphatic and aromatic hydrocarbon compounds of the diesel were retained within the top 5 cm chalk layer and none of the targeted hydrocarbons were detected in the leachate from the four particles sizes chalk. Further to this, the results showed that the chalk is capable of holding more hydrocarbons than sand and chalk can limit their migration of hydrocarbons. The numerical results and the Monte Carlo analysis showed that the migration of the alkanes and PAHs is greatly retarded by the organic carbon in chalk. It is also observed that the initial mass of the alkanes and PAHs and their respective partition coefficients are important for the decaying of the source at the surface immediately after the spill and the rate-limited dissolution is responsible for entrapping the hydrocarbons in the top layer of the chalk. Overall these results can help to better inform risk assessment and help decision for the remediation strategy.en_UK
dc.identifier.citationCao X, Temple T, Li X, et al., (2015) Influence of particle size and organic carbon content on distribution and fate of aliphatic and aromatic hydrocarbon fractions in chalks. Environmental Technology and Innovation, Volume 4, October 2015, pp. 227-239en_UK
dc.identifier.issn2352-1864
dc.identifier.urihttps://doi.org/10.1016/j.eti.2015.09.001
dc.identifier.urihttp://dspace.lib.cranfield.ac.uk/handle/1826/16376
dc.language.isoenen_UK
dc.publisherElsevieren_UK
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAliphatic and PAHsen_UK
dc.subjectDistribution coefficienten_UK
dc.subjectChalken_UK
dc.subjectLeachingen_UK
dc.subjectEnvironmental fate and transport modellingen_UK
dc.subjectMonte Carlo analysisen_UK
dc.titleInfluence of particle size and organic carbon content on distribution and fate of aliphatic and aromatic hydrocarbon fractions in chalksen_UK
dc.typeArticleen_UK

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Influence_of_particle_size-2015.pdf
Size:
1.1 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Staff publications (SWEE)