Effect of dissolved CO2 on the interaction of stress and corrosion for pipeline carbon steels in simulated marine environments

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dc.contributor.authorAbubakar, Shamsuddeen Ashurah
dc.contributor.authorMori, Stefano
dc.contributor.authorSumner, Joy
dc.date.accessioned2023-07-13T13:24:29Z
dc.date.available2023-07-13T13:24:29Z
dc.date.issued2023-06-22
dc.description.abstractOffshore pipelines are subjected to stresses (e.g., from fluid flow, mechanical vibration, and earth movement). These stresses, combined with corrosive environments and in the presence of trace gases (O2, CO2), can increase the pipeline’s corrosion rate and potentially lead to cracking. As such, the impact of trace gases such as CO2 (linked to enhanced oil recovery and carbon capture and sequestration) on corrosion is key to determining whether pipelines are at increased risk. American Petroleum Institute (API) 5L X70 and X100 were exposed as stressed C-rings (80% or 95% of yield strength). The tests were conducted with either N2 (control) or CO2 bubbled through 3.5% NaCl, at either 5 °C or 25 °C. Linear polarization resistance was used to assess corrosion rate, while morphology and variation were determined using optical microscopy (generating metal loss distributions) and scanning electron microscopy. The control experiment (N2) showed that corrosion rates correlated with temperature and stress. In this low O2 environment, both alloys showed similar trends. Under CO2 exposure, all samples showed accelerated corrosion rates; furthermore, the morphologies generated were different for the two alloys: undercutting corrosion with discontinuous microcracks (X70) or deep, wide ellipses (X100). Understanding these changes in corrosion response is key when selecting materials for specific operational environments.en_UK
dc.identifier.citationAbubakar SA, Mori S, Sumner J. (2022) Effect of dissolved CO2 on the interaction of stress and corrosion for pipeline carbon steels in simulated marine environments. Metals, Volume 13, Issue 7, June 2023, Article number 1165en_UK
dc.identifier.issn2075-4701
dc.identifier.urihttps://doi.org/10.3390/met13071165
dc.identifier.urihttps://dspace.lib.cranfield.ac.uk/handle/1826/19988
dc.language.isoenen_UK
dc.publisherMDPIen_UK
dc.rightsAttribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectstressen_UK
dc.subjecttrace gasesen_UK
dc.subjectpipeline carbon steelsen_UK
dc.subjectlinear polarization resistanceen_UK
dc.subjectcumulative probabilityen_UK
dc.subjectcorrosion morphologyen_UK
dc.titleEffect of dissolved CO2 on the interaction of stress and corrosion for pipeline carbon steels in simulated marine environmentsen_UK
dc.typeArticleen_UK

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