Accidents caused by hazardous materials released in an urban environment: a numerical and experimental approach.

This research studies the transport and dispersion of hazardous materials after a fire accident in an urban setting and the unpredictable threats provoked for the population and the environment. A fire accident may result, inter alia, from industrial activity or during the transportation of hazardous materials, such as diesel, petrol or kerosene liquids. In the current research, mineral oil pool fire accidents are examined in order to define the toxic smoke zones at different urban scale geometries. Three different urban scale geometries are examined: a) an isolated building, b) a street canyon and c) a staggered array of urban blocks. The fluid flow, the hazardous dispersion and the safety limits are studied using the Computational Fluid Dynamics (CFD) techniques and wind tunnel experiments. The Computational simulations were conducted using the CFD solver of Fluent and the Fire Dynamic Simulator (FDS). Both Reynolds-average Navier-Stokes (RANS) modes and Large Eddy Simulations (LES) methods were applied. Wind tunnel experiments were conducted in order to better understand the flow around these geometries and evaluate them with LES models. The numerical models were validated with wind tunnel experiments and with additional experimental data selected from the bibliography. The numerical results defined the toxic smoke limits and allowed the creation of simplified risk maps. The latter can define the mitigation measures after a fire accident.