Optical Gas Sensor Fabrication Based on Porphyrin-Anchored Electrostatic Self-Assembly onto Tapered Optical Fibers

dc.contributor.authorJarzebinska, Renata-
dc.contributor.authorKorposh, Sergiy-
dc.contributor.authorJames, Stephen W.-
dc.contributor.authorBatty, William J.-
dc.contributor.authorTatam, Ralph P.-
dc.contributor.authorLee, Seung-Woo-
dc.date.accessioned2014-01-30T17:57:24Z
dc.date.available2014-01-30T17:57:24Z
dc.date.issued2012-07-31T00:00:00Z-
dc.description.abstractTapered optical fibers with nano-assembled coatings of thicknesses of order tens of nanometres were used for the detection of ammonia gas. The film coating was composed of alternate layers of tetrakis-(4-sulfophenyl) porphine (TSPP) and poly(allylamine hydrochloride) (PAH), which were deposited using the electrostatic self-assembly process (ESA). Exposure of a PAH/TSPP nano-assembled non-adiabatic tapered optical fiber with a waist diameter of 10µm to ammonia induced significant optical changes in the transmission spectrum of the optical fiber. The fiber optic sensor showed a linear sensitivity to the concentration of ammonia in the range of 10-100ppm, with response and recovery times less than 100 and 240sec, respectively. The 3σ limit of detection (LOD) was estimated to be ca. 2ppm.en_UK
dc.identifier.citationRenata Jarzebinska, Sergiy Korposh, Stephen James, William Batty, Ralph Tatam and Seung-Woo Lee, Optical Gas Sensor Fabrication Based on Porphyrin-Anchored Electrostatic Self-Assembly onto Tapered Optical Fibers, Analytical Letters, Volume 45, Issue 10, 2012, Pages 1297-1309.
dc.identifier.issn0003-2719-
dc.identifier.urihttp://dx.doi.org/10.1080/00032719.2012.673097-
dc.identifier.urihttp://dspace.lib.cranfield.ac.uk/handle/1826/8215
dc.publisherTaylor & Francisen_UK
dc.rightsThis is a postprint of an article whose final and definitive form has been published in the Analytical Letters 2012 copyright Taylor & Francis; Analytical Letters is available online at: http://www.tandfonline.com/doi/abs/10.1080/00032719.2012.673097#.UuuBSLS0CW9
dc.titleOptical Gas Sensor Fabrication Based on Porphyrin-Anchored Electrostatic Self-Assembly onto Tapered Optical Fibersen_UK
dc.typeArticle-

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