Formation and Structural Characterization of Metal Complexes derived from Thiosalicylic acid

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dc.contributor.authorBhowon, M G
dc.contributor.authorJhaumeer-Laulloo, S
dc.contributor.authorMoosun, S
dc.contributor.authorHumphreys, L
dc.contributor.authorColes, S
dc.contributor.authorFowdram, R
dc.contributor.authorMungra, E
dc.date.accessioned2017-09-20T14:36:47Z
dc.date.available2017-09-20T14:36:47Z
dc.date.issued2017-09-01
dc.description.abstractThe formation and structural aspects of some metal complexes of thiosalicylic acid (TSA) were studied. The µ-bridging tetra-coordinated Ru complex, [Ru(C6H4(CO2)(µ-S)(H2O)]2 (1) was formed by hydrothermal reaction of TSA with RuCl3. The complexes [M(dtdb)(phen)(H2O)]n (2-4) (M= Zn(II), Co(II), Ni(II), dtdb = 2,2’-dithiodibenzoate anion, phen = 1,10-phenanthroline) were obtained by the slow diffusion technique and the in situ S-S bond formation was confirmed by elemental, spectral and X-ray analysis. Reaction of TSA with CuCl2 and 2,2’-bipyridine (bipy) under the slow diffusion technique yielded the dimer [Cu(tdb)(bipy)] (5) (tdb = thiodibenzoic acid) where the in-situ generation of 2,2’-thiodibenzoic acid was observed.en_UK
dc.identifier.citationBhowon MG, Jhaumeer-Laulloo S, Moosun S, et al., (2017) Formation and Structural Characterization of Metal Complexes derived from Thiosalicylic acid. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, Volume 643, Issue 18, October 2017, pp. 1167-1172en_UK
dc.identifier.urihttps://doi.org/10.1002/zaac.201700244
dc.identifier.urihttp://dspace.lib.cranfield.ac.uk/handle/1826/12523
dc.language.isoenen_UK
dc.publisherWiley - VCH Verlagen_UK
dc.rightsAttribution-NonCommercial 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.titleFormation and Structural Characterization of Metal Complexes derived from Thiosalicylic aciden_UK
dc.typeArticleen_UK

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