Abstract:
Pharmaceutical residues gain importance as they are emitted in a vast array and quantity
into the aquatic environment. The main source for most pharmaceuticals are the discharges
of wastewater treatment plants. Within this study four WTPs were selected with different
biological treatment processes, such as rotating biological contactor (RBC), trickling filter
(TF), activated sludge plant (ASP) and oxidation ditch (OD). Samples were taken each
possible treatment step and analysed for their content of Triclosan and Tetracycline and
selected biomass and wastewater characteristics were also determined.
Tetracycline could not be detected in any of the wastewater treatment plants, nor its
degradation products, which might be suggested to their chelating nature with divalent
cations, such as calcium and metals. Triclosan has been detected in almost every liquid
sample of the wastewater treatment in concentrations up to 5,000 ngL-1 for influents and
800 ngL-1 for effluents.
In principle it is problematic to compare elimination rates for different wastewater treatment
plants, as their influent conditions may often show wide variations. However, loss rates for
Triclosan within the four different treatment systems varied between 81% and 96%, showing
the best and most consistent elimination rate for the oxidation ditch.
Although Triclosan removal rates are shown to be significant high, discharges still contained
substantial residual concentrations, which would therefore require further elimination steps.
Triclosan amounts bound to extracellular polymeric substances seemed to adversely a.ect
discharge values. This is most likely due to the desorption processes occurring in the
secondary clarifier.
The correlation between liquid and biomass characteristics are weak to moderate, probably
due to influences of uncontrolled factors associated with the operation of a full scale treatment
work system from which all the samples were obtained. Among all of the determined
liquid and biomass characteristics temperature, pH and lipid content showed themselves to
be the most significant, with regards to the overall removal of Triclosan. Furthermore, few
parameters, such as chemical oxyen demand or specific oxygen demand* within influent
or oxidation ditch samples seemed to have impact on either Triclosan concentration of the
bulk phase of the oxidation ditch or the Triclosan uptake within the EPS.
