dc.description.abstract |
This thesis describes two novel techniques for the metallization of
non-electroactive polymer films and thicker sectioned polyethylene and nylon
substrates.
In the first approach, non-electroactive polymer substrates were impregnated
with surface layers of polypyrrole and polyaniline, using electrochemical and chemical
methods of polymerization. The relative merits of both these approaches are discussed
and compared with other methods in the literature. The resultant composite materials
exhibited sufficient conductivity to permit the direct electrodeposition of metal surface
coats. Polypyrrole coated substrates were also metallized using chemical methods.
Cyclic voltammetry studies and scanning electron microscopy of metal coated
polypyrrole, showed that metal deposition occurred mainly at the polymer surface by
a mechanism of instantaneous nucleation and growth. Using optimized deposition
conditions, both electrochemical and chemical metal deposition methods were used to
deposit highly reflecting and coherent metal layers onto conducting polymer coated
materials.
The second approach of metallizing polymers, was the metallization of
non-electroactive polymer films by the electroreduction of silver from non-aqueous
based silver plating solutions. The effects of the electrode substrate, the deposition
potential, and the concentration of metal ions in solution were investigated to
determine suitable metal salt/solvent, and polymer film/solvent combinations. The
resultant metallized polymer films were evaluated using optical and scanning electron
microscopy, ac impedance, and reflectance measurements. These studies enabled the
optimum deposition conditions to be determined, and these were subsequently used
for the preparation of high quality, uniform, and reflective metal coated films.
The results for the electrodeposition of silver into polymer films using the
latter approach are compared with those obtained from alternative electrochemical and
chemical methods of metallizing polymer films. |
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