Investigating residue dissolution of insensitive high explosives in two sandy soil types: a predictive modelling approach

The demand for munitions that are less likely to detonate accidentally has led to an increased use of Insensitive High Explosives (IHE), which contain substances like 2,4-dinitroanisole (DNAN) and 5-nitro-1,2,4-triazol-3-one (NTO). These substances have different properties compared to traditional explosives, and their potential environmental impact is not well understood. When these explosives are used in live-fire training exercises, their residues end up in the soil. It is important to determine how these residues dissolve and enter the soil. This study aimed to experimentally measure the rate at which an IHE formulation dissolves when exposed to rainwater with pH levels of 5.0 and 6.5, and to simulate how these residues dissolve and move through two different soil types. The dissolution rates were determined by conducting experiments in which IHE particles (30–60 mg) were exposed to water with varying pH levels and temperatures. The results showed that the dissolution rate of NTO did not vary with pH, while the dissolution rate of DNAN and RDX decreased with decreasing pH. Specifically, the dissolution rate of DNAN decreased from 18 ± 40 μg min−1 at pH 6.5 to 6 ± 4 μg min−1 at pH 5.0, while the dissolution rate of RDX decreased from 8 ± 4 to 3 ± 1 μg min−1. These findings were used to develop a stochastic model that successfully simulated the concentration of IHE in the leachate from soil columns over time. A sensitivity analysis revealed that while dissolution rates determined the amount of mass entering the soil, they did not significantly regulate the amount of mass that migrated through the soil and leached out of the soil columns.