Chemical vapour deposition of freestanding sub-60 nm graphene gyroids

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dc.contributor.author Cebo, Tomasz
dc.contributor.author Aria, Adrianus Indrat
dc.contributor.author Dolan, James A.
dc.contributor.author Weatherup, Robert S.
dc.contributor.author Nakanishi, Kenichi
dc.contributor.author Kidambi, Piran R.
dc.contributor.author Divitini, Giorgio
dc.contributor.author Ducati, Caterina
dc.contributor.author Steiner, Ullrich
dc.contributor.author Hofmann, Stephan
dc.date.accessioned 2018-08-13T15:59:38Z
dc.date.available 2018-08-13T15:59:38Z
dc.date.issued 2017-12-18
dc.identifier.citation Cebo T, Aria AI, Dolan JA, et al., Chemical vapour deposition of freestanding sub-60 nm graphene gyroids, Applied Physics Letters, Vol. 111, Issue 25, 2017, Article number 253103 en_UK
dc.identifier.issn 0003-6951
dc.identifier.uri http://dx.doi.org/10.1063/1.4997774
dc.identifier.uri http://dspace.lib.cranfield.ac.uk/handle/1826/13396
dc.description.abstract The direct chemical vapour deposition of freestanding graphene gyroids with controlled sub-60 nm unit cell sizes is demonstrated. Three-dimensional (3D) nickel templates were fabricated through electrodeposition into a selectively voided triblock terpolymer. The high temperature instability of sub-micron unit cell structures was effectively addressed through the early introduction of the carbon precursor, which stabilizes the metallized gyroidal templates. The as-grown graphene gyroids are self-supporting and can be transferred onto a variety of substrates. Furthermore, they represent the smallest free standing periodic graphene 3D structures yet produced with a pore size of tens of nm, as analysed by electron microscopy and optical spectroscopy. We discuss generality of our methodology for the synthesis of other types of nanoscale, 3D graphene assemblies, and the transferability of this approach to other 2D materials. en_UK
dc.language.iso en en_UK
dc.publisher AIP Publishing en_UK
dc.rights Attribution-NonCommercial 4.0 International *
dc.rights.uri http://creativecommons.org/licenses/by-nc/4.0/ *
dc.subject Gyroid
dc.subject Graphene foam
dc.subject Free-standing graphene
dc.subject Graphene nanostructure
dc.subject CVD
dc.subject Template stability
dc.subject Precursor predosing
dc.subject Block copolymer self-assembly
dc.title Chemical vapour deposition of freestanding sub-60 nm graphene gyroids en_UK
dc.type Article en_UK


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