Abstract:
Struvite causes maintenance, and operational problems due to fouling in wastewater
and sludge treatment systems. Struvite formation was initially investigated using a
series of jar tests on real and synthetic sludge liquors. A computer model predicting
struvite precipitation potential was compared to the results generated. Struvite
formation was found to be closely linked to pH with increasing pH resulting in
decreasing struvite solubility.
Further studies analysed the relationship between a solutions' supersaturation ratio,
material and the scaling rate. Tests were undertaken at 3 supersaturation ratios with 3
different materials: stainless steel, Teflon and acrylic. Acrylic and Teflon coupons
were scientifically roughened to show the influence that surface roughness has on a
materials' scaling propensity.
The control of struvite precipitation was investigated using a range of chemical
inhibitors and chelating agents. Experiments using the same materials used
previously were performed with a range of scale inhibitors and chelating agents. The
scale inhibitors did not prevent struvite from forming, with only one product,
Polystabilis, showing a reduction in the mass of scale formed on the impellers. Of the
chelating agents tested, EDTA was the most effective even in alkaline conditions and
was shown to have the ability to re-dissolve struvite previously formed on materials.
