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Item Open Access Silvoarable agroforestry(The Royal Scottish Forestry Society, 1999-01-01) Beaton, A.; Incoll, L. D.; Burgess, Paul J.Introduction: A silvoarable system of land management implies the cultivation of trees and arable crops on the same area of land, a system practised quite commonly in southern Europe and in the tropics. The system comprises two components: tree rows, generally one tree wide, and arable alleys, alternating across the field. The first major development of silvoarable practice in the UK took place during the 1960s and 1970s when Bryant & May established extensive poplar plantations on lowland farmland in southern England to supply their own market for match veneer timber (Beaton, 1987). Since the demise of the Bryant Sr May market for match timber in 1978, interest in the potential for silvoarable systems lay dormant until the advent of food crop surpluses in the 1980s.Item Open Access Intelligent imaging systems for automotive applications(SPIE, 2003-03-31) Thompson, Chris; Huang, Yingping; Fu, ShanIn common with many other application areas, visual signals are becoming an increasingly important information source for many automotive applications. For several years CCD cameras have been used as research tools for a range of automotive applications. Infrared cameras, RADAR and LIDAR are other types of imaging sensors that have also been widely investigated for use in cars. This paper will describe work in this field performed in C2VIP over the last decade - starting with Night Vision Systems and looking at various other Advanced Driver Assistance Systems. Emerging from this experience, we make the following observations which are crucial for "intelligent" imaging systems: 1. Careful arrangement of sensor array. 2. Dynamic-Self-Calibration. 3. Networking and processing. 4. Fusion with other imaging sensors, both at the image level and the feature level, provides much more flexibility and reliability in complex situations. We will discuss how these problems can be addressed and what are the outstanding issues.Item Open Access Report of Committee III.2: fatigue and fracture(Elsevier, 2003-12-31) Brennan, Feargal P.COMMITTEE MANDATE Concern for crack initiation and growth under cyclic loading as well as unstable crack propagation and tearing in ship and offshore structures. Due attention shall be paid to practical application and statistical description of fracture control methods in design, fabrication and service. Consideration is to be given to the suitability and uncertainty of physical models. The work shall be coordinated with that of Committee V.2.Item Unknown Difficulties in using spectral properties to map irrigated areas in a temperate climate: A case study of potatoes in England(2008) Shamal, S.; Weatherhead, E. K.; Knox, Jerry W.Irrigation in England is supplemental to rainfall and only used on a small proportion of the cultivated land, notably on high value vegetable and potato crops. However, it is a significant water user as most of the irrigated area is located in the driest part of England. The existing data on irrigated areas are based on government and industry surveys. Recently these datasets have been used with Geographic Information Systems (GIS) to produce irrigated maps, but these can only be published at catchment level due to confidentiality constraints on the datasets. To assess the possibility of using remote sensing data for mapping the irrigated area, one Landsat image for the summer 2003 was used to compare the spectral signature between irrigated and non-irrigated potato fields in the East of England. ISODATA algorithm was used to perform unsupervised classification, and 50 spectral classes were created. A ground truth dataset was then used to identify the most representative spectral class for irrigated and nonirrigated fields. The result showed that categories both fall into the same spectral class, suggesting there are no significant differences between their spectral properties. Therefore, using satellite imagery may not yet be an appropriate method or need more research for mapping irrigated area in temperate climates such as England. The summer rainfall reduces the water stress differences between irrigated and non-irrigated potato fields such that these satellite sensors cannot yet differentiate the crops.Item Open Access Neural predictive control of broiler chicken growth(Elsevier, 2010-12-31) Demmers, Theo G. M.; Cao, Yi; Gauss, Sophie; Lowe, John C.; Parsons, David J.; Wathes, Christopher M.Active control of the growth of broiler chickens has potential benefits for farmers in terms of improved production efficiency, as well as for animal welfare in terms of improved leg health. In this work, a differential recurrent neural network (DRNN) was identified from experimental data to represent broiler chicken growth using a recently developed nonlinear system identification algorithm. The DRNN model was then used as the internal model for nonlinear model predicative control (NMPC) to achieve a group of desired growth curves. The experimental results demonstrated that the DRNN model captured the underlying dynamics of the broiler growth process reasonably well. The DRNN based NMPC was able to specify feed intakes in real time so that the broiler weights accurately followed the desired growth curves ranging from $-12%$ to +12% of the standard curve. The overall mean relative error between the desired and achieved broiler weight was 1.8% for the period from day 12 to day 51.Item Open Access Avocado firmness monitoring with values obtained by means of laser doppler vibrometry(International Society for Horticultural Science, 2012-04-01) Terry, Leon A.; Landahl, SandraAvocado (Persea americana Mill.) ripeness is usually evaluated by destructive firmness assessment, yet quality is notorious for being heterogeneous within a consignment. This problem, which is especially true for imported avocado fruit, lends itself to searching for non-destructive methods for firmness evaluation. Firmness of objects can be analysed by impulse-response. This technique utilizes recording of a vibration signature and interpretation of the resonant frequency. In this study a laser Doppler vibrometer (LDV) was used for non-contact recording. The aim of this study was to show the feasibility of using a LDV to monitor avocado firmness. In order to create avocado batches of different homogeneity, three groups were treated with and without ethylene, inside or outside a box. After day 0 a third of the fruit were transferred into boxes (325 L) to be treated with ethylene for 24 h. A third was kept in boxes untreated and another third was kept on open trays. Avocado fruit cultivar ‘Hass’ were ripened at 18°C and measured on days 0, 2, 3, 4 and 6. Individual fruit were impacted once and two LDV measurements were taken simultaneously at the stem-end and seed-end. This was repeated twice around the fruit. Force-deformation measurements in compression mode were performed by means of uniaxial testing (Instron model 5542) on two opposite sides (day 0 n=8, then n=24 i.e., 8 per treatment/d). Significant differences were found between firmness of avocados over time and across treatments. Firmness decreased exponentially as expected (304.1 to 2.1 N) over six days. The LDV results showed significant differences between days, treatments and laser-location. The resonant frequency of the fruit decreased linearly until day 4 and then decreased more slowly (1671 to 476 Hz). On average, the frequency found at the seed-end of the fruit was higher than the resonant frequency at the stem-end. This is thought to be due to the seed itself, which could influence the vibration pattern. Resonant frequencies showed good correlation to the logarithm of firmness (r=0.87) and therefore were shown capable of monitoring avocado firmness.Item Open Access Priorities for sustainable turfgrass management: a research and industry perspective(Taylor and Francis, 2012-05-24) Strandberg, M.; Blombäck, K.; Dahl Jensen, A. M.; Knox, Jerry W.This paper provides a brief review and assessment of the key environmental, regulatory and technical issues facing the turfgrass sector with specific reference to the European context. It considers the range of externalities or ‘drivers for change' facing the industry, and the challenges and opportunities available for promoting and achieving more sustainable turfgrass management within the sports, landscape and amenity sectors. The analysis confirms that there are a number of key areas where a concerted research and industrial effort is required. These include responding to the pressures from government demands for greater environmental regulation, the increasing pressure on natural resources (notably water, energy and land), the emerging role of turf management in supporting ecosystem services and enhancing biodiversity, the continued need to promote integrated pest management, and the looming challenges posed by a changing climate, and urgent need to adapt. Whilst many of these externalities appear to be risks to the sports turf industry, there will also be significant opportunities, for those where the labour, energy and agronomic costs are minimized and where the drive to adopt a multifunctional approach to sportsturf management is embraced.Item Open Access Blade design optimisation for fixed-pitch fixed-speed wind turbines(Hindawi Publishing Corporation, 2012-07) Wang, Lin; Tang, Xinzi; Liu, XiongweiFixed-pitch fixed-speed (FPFS) wind turbines have some distinct advantages over other topologies for small wind turbines, particularly for low wind speed sites. The blade design of FPFS wind turbines is fundamentally different to fixed-pitch variable-speed wind turbine blade design. Theoretically, it is difficult to obtain a global mathematical solution for the blade design optimisation. Through case studies of a given baseline wind turbine and its blade airfoil, this paper aims to demonstrate a practical method for optimum blade design of FPFS small wind turbines. The optimum blade design is based on the aerodynamic characteristics of the airfoil, that is, the lift and drag coefficients, and the annual mean wind speed. The design parameters for the blade optimisation include design wind speed, design tip speed ratio, and design attack angle. A series of design case studies using various design parameters are investigated for the wind turbine blade design. The design outcomes are analyzed and compared to each other against power performance of the rotor and annual energy production. The design outcomes from the limited design cases demonstrate clearly which blade design provides the best performance. This approach can be used for any practice of FPFS wind turbine blade design and refurbishment.Item Open Access Prediction of ‘Nules Clementine’ mandarin susceptibility to rind breakdown disorder using Vis/NIR spectroscopy(Elsevier, 2012-07-15) Magwaza, Lembe Samukelo; Opara, Umezuruike Linus; Terry, Leon A.; Landahl, Sandra; Cronje, Paul J.; Nieuwoudt, Helene; Mouazen, Abdul Mounem; Saeys, Wouter; Nicolai, Bart M.The use of diffuse reflectance visible and near infrared (Vis/NIR) spectroscopy was explored as a non-destructive technique to predict ‘Nules Clementine’ mandarin fruit susceptibility to rind breakdown (RBD) disorder by detecting rind physico-chemical properties of 80 intact fruit harvested from different canopy positions. Vis/NIR spectra were obtained using a LabSpec® spectrophotometer. Reference physico-chemical data of the fruit were obtained after 8 weeks of storage at 8 °C using conventional methods and included RBD, hue angle, colour index, mass loss, rind dry matter, as well as carbohydrates (sucrose, glucose, fructose, total carbohydrates), and total phenolic acid concentrations. Principal component analysis (PCA) was applied to analyse spectral data to identify clusters in the PCA score plots and outliers. Partial least squares (PLS) regression was applied to spectral data after PCA to develop prediction models for each quality attribute. The spectra were subjected to a test set validation by dividing the data into calibration (n = 48) and test validation (n = 32) sets. An extra set of 40 fruit harvested from a different part of the orchard was used for external validation. PLS-discriminant analysis (PLS-DA) models were developed to sort fruit based on canopy position and RBD susceptibility. Fruit position within the canopy had a significant influence on rind biochemical properties. Outside fruit had higher rind carbohydrates, phenolic acids and dry matter content and lower RBD index than inside fruit. The data distribution in the PCA and PLS-DA models displayed four clusters that could easily be identified. These clusters allowed distinction between fruit from different preharvest treatments. NIR calibration and validation results demonstrated that colour index, dry matter, total carbohydrates and mass loss were predicted with significant accuracy, with residual predictive deviation (RPD) for prediction of 3.83, 3.58, 3.15 and 2.61, respectively. The good correlation between spectral information and carbohydrate content demonstrated the potential of Vis/NIR as a non-destructive tool to predict fruit susceptibility to RBD.Item Open Access Indicators of soil quality - Physical properties (SP1611). Final report to Defra(Defra, 2012-09-30) Rickson, R. Jane; Deeks, Lynda K.; Corstanje, Ronald; Newell-Price, Paul; Kibblewhite, Mark G.; Chambers, B.; Bellamy, Patricia; Holman, Ian P.; James, I. T.; Jones, Robert; Kechavarsi, C.; Mouazen, Abdul; Ritz, K.; Waine, TobyThe condition of soil determines its ability to carry out diverse and essential functions that support human health and wellbeing. These functions (or ecosystem goods and services) include producing food, storing water, carbon and nutrients, protecting our buried cultural heritage and providing a habitat for flora and fauna. Therefore, it is important to know the condition or quality of soil and how this changes over space and time in response to natural factors (such as changing weather patterns) or to land management practices. Meaningful soil quality indicators (SQIs), based on physical, biological or chemical soil properties are needed for the successful implementation of a soil monitoring programme in England and Wales. Soil monitoring can provide decision makers with important data to target, implement and evaluate policies aimed at safeguarding UK soil resources. Indeed, the absence of agreed and well-defined SQIs is likely to be a barrier to the development of soil protection policy and its subsequent implementation. This project assessed whether physical soil properties can be used to indicate the quality of soil in terms of its capacity to deliver ecosystem goods and services. The 22 direct (e.g. bulk density) and 4 indirect (e.g. catchment hydrograph) physical SQIs defined by Loveland and Thompson (2002) and subsequently evaluated by Merrington et al. (2006), were re-visited in the light of new scientific evidence, recent policy drivers and developments in sampling techniques and monitoring methodologies (Work Package 1). The culmination of these efforts resulted in 38 direct and 4 indirect soil physical properties being identified as potential SQIs. Based on the gathered evidence, a ‘logical sieve’ was used to assess the relative strengths, weaknesses and suitability of each potential physical SQI for national scale soil monitoring. Each soil physical property was scored in terms of: soil function – does the candidate SQI reflect all soil function(s)? land use - does the candidate SQI apply to all land uses found nationally? soil degradation - can the candidate SQI express soil degradation processes? does the candidate SQI meet the challenge criteria used by Merrington et al. (2006)?This approach enabled a consistent synthesis of available information and the semi-objective, semi-quantitative and transparent assessment of indicators against a series of scientific and technical criteria (Ritz et al., 2009; Black et al., 2008). The logical sieve was shown to be a flexible decision-support tool to assist a range of stakeholders with different agenda in formulating a prioritised list of potential physical SQIs. This was explored further by members of the soil science and soils policy community at a project workshop. By emphasising the current key policy-related soil functions (i.e. provisioning and regulating), the logical sieve was used to generate scores which were then ranked to identify the most qualified SQIs. The process selected 18 candidate physical SQIs. This list was further filtered to move from the ‘narrative’ to a more ‘numerical’ approach, in order to test the robustness of the candidate SQIs through statistical analysis and modelling (Work Package 2). The remaining 7 physical SQIs were: depth of soil; soil water retention characteristics; packing density; visual soil assessment / evaluation; rate of erosion; sealing; and aggregate stability. For these SQIs to be included in a robust national soil monitoring programme, we investigated the uncertainty in their measurement; the spatial and temporal variability in the indicator as given by observed distributions; and the expected rate of change in the indicator. Whilst a baseline is needed (i.e. the current state of soil), it is the rate of change in soil properties and the implications of that change in terms of soil processes and functioning that are key to effective soil monitoring. Where empirical evidence was available, power analysis was used to understand the variability of indicators as given by the observed distributions. This process determines the ability to detect a particular change in the SQI at a particular confidence level, given the ‘noise’ or variability in the data (i.e. a particular power to detect a change of ‘X’ at a confidence level of ‘Y%’ would require ‘N’ samples). However, the evidence base for analysing the candidate SQIs is poor: data are limited in spatial and temporal extent for England and Wales, in terms of a) the degree (magnitude) of change in the SQI which significantly affects soil processes and functions (i.e. ‘meaningful change’), and b) the change in the SQI that is detectable (i.e. what sample size is needed to detect the meaningful signal from the variability or noise in the signal). This constrains the design and implementation of a scientifically and statistically rigorous and reliable soil monitoring programme. Evidence that is available suggests that what constitutes meaningful change will depend on soil type, current soil state, land use and the soil function under consideration. However, when we tested this by analysing detectable changes in packing density and soil depth (because data were available for these SQIs) over different land covers and soil types, no relationships were found. Schipper and Sparling (2000) identify the challenge: “a standardised methodology may not be appropriate to apply across contrasting soils and land uses. However, it is not practical to optimise sampling and analytical techniques for each soil and land use for extensive sampling on a national scale”. Despite the paucity in data, all seven SQIs have direct relevance to current and likely future soil and environmental policy, because they can be related (qualitatively) to soil processes, soil functions and delivery of ecosystem goods and services. Even so, meaningful and detectable changes in physical SQIs may be out of time with any soil policy change and it is not usually possible to link particular changes in SQIs to particular policy activities. This presents challenges in ascertaining trends that can feed into policy development or be used to gauge the effectiveness of soil protection policies (Work Package 3). Of the seven candidate physical SQIs identified, soil depth and surface sealing are regarded by many as indicators of soil quantity rather than quality. Visual soil evaluation is currently not suited to soil monitoring in the strictest sense, as its semi-qualitative basis cannot be analysed statistically. Also, few data exist on how visual evaluation scores relate to soil functions. However, some studies have begun to investigate how VSE might be moved to a more quantified scale and the method has some potential as a low cost field technique to assess soil condition. Packing density requires data on bulk density and clay content, both of which are highly variable, so compounding the error term associated with this physical SQI. More evidence is needed to show how ‘meaningful’ change in aggregate stability affects soil processes and thus soil functions (for example, using the limited data available, an equivocal relationship was found with water regulation / runoff generation). The analysis of available data has given promising results regarding the prediction of soil water retention characteristics and packing density from relatively easy to measure soil properties (bulk density, texture and organic C) using pedotransfer functions. Expanding the evidence base is possible with the development of rapid, cost-effective techniques such as NIR sensors to measure soil properties. Defra project SP1303 (Brazier et al., 2012) used power analyses to estimate the number of monitoring locations required to detect a statistically significant change in soil erosion rate on cultivated land. However, what constitutes a meaningful change in erosion rates still requires data on the impacts of erosion on soil functions. Priority cannot be given amongst the seven SQIs, because the evidence base for each varies in its robustness and extent. Lack of data (including uncertainty in measurement and variability in observed distributions) applies to individual SQIs; attempts at integrating more than one SQI (including physical, biological and chemical SQIs) to improve associations between soil properties and processes / functions are only likely to propagate errors. Whether existing monitoring programmes can be adapted to incorporate additional measurement of physical SQIs was explored. We considered options where one or more of the candidate physical SQIs might be implemented into soil monitoring programmes (e.g. as a new national monitoring scheme; as part of the Countryside Survey; and as part of the National Soil Inventory). The challenge is to decide whether carrying out soil monitoring that is not statistically robust is still valuable in answering questions regarding current and future soil quality. The relationship between physical (and other) SQIs, soil processes and soil functions is complex, as is how this influences ecosystem services’ delivery. Important gaps remain in even the realisation of a conceptual model for these inter-relationships, let alone their quantification. There is also a question of whether individual quantitative SQIs can be related to ecosystem services, given the number of variables.Item Open Access Monitoring of renewable energy yield of mixed wastes by image analysis of input residual waste materials(CISA Publisher, 2012-11) Wagland, Stuart Thomas; Longhurst, Philip J.A novel image analysis method has been developed by Cranfield University. Following on from a recent study, this approach has been applied alongside calorific values and %14C to determine the renewable energy content of mixed wastes. This method determines the composition of the mixed waste material, and then using calorific values and biogenic carbon (14C) content the renewable energy potential of the mixed waste sample can be accurately determined. The correlations between actual (known) weights and composition of the components and the values from the image analysis are compared; these correlations (r ≥0.988) were found to be highly significant (p<0.005). The renewable energy contents (as a % of the total energy) were calculated to be between 0.64 and 3.98 below the actual values. Potential applications for the image analysis tool include a) renewable energy potential of mixed wastes prior to combustion, and b) certification of solid recovered fuels [SRF].Item Open Access Safety assessment of novel polymer-silicon composites - from LCA perspective(Publications Office of the European Union, 2012-12) Zhu, Huijun; Irfan, Adeel; Sachse, Sophia; Njuguna, JamesThe fast growing trend in the development of novel materials with potential applications in many industrial sectors has caused concerns over the environment and human health effect of the emerging activities and associated products. It is imperative that these concerns are addressed in a holistic manner as early as possible. As part of the NEPHH project, this study applied the LCA concept aiming to identify hazardous nanoparticles (NP) that could be released during the development and application of novel products, focusing on polymeric-silicon composites in recognition of their attractions to a wide range of industries, including construct engineering, automotive and aerospace.Item Open Access Modeling of a supercritical power plant with an oxy type pulverized fuel boiler, a carbon dioxide capture unit and a ‘four-end’ type membrane air separator(Polish Academy of Sciences, 2012-12-31) Kotowicz, Janusz; Michalski, SebastianThe analysis of a 600 MW supercritical power plant with parameters of life steam at 30 MPa/ /650o C and of reheated steam 6 MPa/670o C was made. Power plant is equipped with the following units: oxy type pulverized fuel boiler, ‘four-end’ high temperature membrane air separator and carbon dioxide capture system which were modeled. With the assumption of a constant gross power of the analyzed power plant, the thermal efficiency of the boiler and the steam cycle efficiency were calculated. These parameters were designated as a function of the recovery rate of oxygen in the air separation unit. This allowed to determine gross and net efficiency of electricity generation.Item Open Access Influence of compost amendments on the hydraulic functioning of brownfield soils(Wiley, 2013-01-21) Whelan, A.; Kechavarzi, C.; Coulon, Frederic; Sakrabani, Ruben; Lord, R.This study assessed the impact of compost on the hydraulic properties of three soils (sandy loam, clay loam and diesel-contaminated sandy loam) with relatively poor physical quality typical of brownfield sites. Soils were amended with two composts at 750 t/ha. Samples were also collected from a clay-capped brownfield site, previously amended with 250, 500 or 750 t/ha of compost. Water-release characteristics and saturated hydraulic conductivity were determined for all soils and physical quality indicators derived. Unsaturated flow in field profiles after compost application with two depths of incorporation and two indigenous subsoils was simulated using Hydrus-1D. Compost generally increased water retention. Hydraulic conductivity tended to decrease following compost application in sandy loam but increased in clay and clay loam, where compost addition resulted in a larger dominant pore size. Although compost improved physical quality indicators, they remained suboptimum in clay and clay loam soil, which exhibited poor aeration, and in the contaminated sandy loam, where available water capacity was limited, possibly due to changes in wettability. Increasing application rates in the field enhanced water retention at low potentials and hydraulic conductivity near saturation but did not alter physical quality indicators. Numerical simulation indicated that the 500 t/ha application resulted in the best soil moisture regime. Increasing the depth of incorporation in the clay cap improved drainage and reduced waterlogging, but incorporation in more permeable subsoil resulted in prolonged dry conditions to greater depths.Item Open Access Quantifying the loss of methane through secondary gas mass transport (or 'slip') from a micro-porous membrane contactor applied to biogas upgrading(IWA Publishing, 2013-04-29) McLeod, Andrew J.; Jefferson, Bruce; McAdam, Ewan J.Secondary gas transport during the separation of a binary gas with a micro-porous hollow fibre membrane contactor (HMFC) has been studied for biogas upgrading. In this application, the loss or ‘slip' of the secondary gas (methane) during separation is a known concern, specifically since methane possesses the intrinsic calorific value. Deionised (DI) water was initially used as the physical solvent. Under these conditions, carbon dioxide (CO2) and methane (CH4) absorption were dependent upon liquid velocity (VL). Whilst the highest CO2 flux was recorded at high VL, selectivity towards CO2 declined due to low residence times and a diminished gas-side partial pressure, and resulted in slip of approximately 5.2% of the inlet methane. Sodium hydroxide was subsequently used as a comparative chemical absorption solvent. Under these conditions, CO2 mass transfer increased by increasing gas velocity (VG) which is attributed to the excess of reactive hydroxide ions present in the solvent, and the fast conversion of dissolved CO2 to carbonate species reinitiating the concentration gradient at the gas-liquid interface. At high gas velocities, CH4 slip was reduced to 0.1% under chemical conditions. Methane slip is therefore dependent upon whether the process is gas phase or liquid phase controlled, since methane mass transport can be adequately described by Henry's law within both physical and chemical solvents. The addition of an electrolyte was found to further retard CH4 absorption via the salting out effect. However, their applicability to physical solvents is limited since electrolytic concentration similarly impinges upon the solvents' capacity for CO2. This study illustrates the significance of secondary gas mass transport, and furthermore demonstrates that gas-phase controlled systems are recommended where greater selectivity is required,Item Open Access Soil organic carbon and root distribution in a temperate arable agroforestry system(Springer, 2013-06-01) Upson, Matthew A.; Burgess, Paul J.Aim To determine, for arable land in a temperate area, the effect of tree establishment and intercropping treatments, on the distribution of roots and soil organic carbon to a depth of 1.5 m. Methods A poplar (Populus sp.) silvoarable agroforestry experiment including arable controls was established on arable land in lowland England in 1992. The trees were intercropped with an arable rotation or bare fallow for the first 11 years, thereafter grass was allowed to establish. Coarse and fine root distributions (to depths of up to 1.5 m and up to 5 m from the trees) were measured in 1996, 2003, and 2011. The amount and type of soil carbon to 1.5 m depth was also measured in 2011. Results The trees, initially surrounded by arable crops rather than fallow, had a deeper coarse root distribution with less lateral expansion. In 2011, the combined length of tree and understorey vegetation roots was greater in the agroforestry treatments than the control, at depths below 0.9 m. Between 0 and 1.5 m depth, the fine root carbon in the agroforestry treatment (2.56 t ha-1) was 79% greater than that in the control (1.43 t ha-1). Although the soil organic carbon in the top 0.6 m under the trees (161 t C ha-1) was greater than in the control (142 t C ha-1), a tendency for smaller soil carbon levels beneath the trees at lower depths, meant that there was no overall tree effect when a 1.5 m soil depth was considered. From a limited sample, there was no tree effect on the proportion of recalcitrant soil organic carbon. Conclusions The observed decline in soil carbon beneath the trees at soil depths greater than 60 cm, if observed elsewhere, has important implication for assessments of the role of afforestation and agroforestry in sequestering carbon.Item Open Access Water savings in irrigated agriculture - a framework for assessing technology and management options to reduce water losses(IP Publishing, 2013-06-01) Hess, Tim M.; Knox, Jerry W.;Water savings in agriculture often refer to reducing the amount of water abstracted or diverted and used for different purposes. However, this is not the only option as reductions in water use can also be achieved by using appropriate techniques for irrigation, applying relevant management practices, using water from alternative sources or influencing behaviour, for example via awareness-raising, dissemination of best practices, regulation, water pricing and/or using financial incentives. Whilst these options or responses will help reduce pressure on water resources, if implemented in isolation they limit the extent to which water is actually ‘saved'. More often they need to be considered as part of a broader integrated approach to water management. This paper presents a framework for identifying areas where scope for achieving water savings exist, and then briefly reviews the possible means of action and constraints to implementation. The framework is intended to inform polices aimed at improving the sustainability and allocation of water to irrigated agriculture.Item Open Access Ultrasound-induced emulsification of subcritical carbon dioxide/water with and without surfactant as a strategy for enhanced mass transport(Elsevier, 2013-06-03) Cenci, Steven M.; Cox, Liam R.; Leeke, Gary A.Pulsed ultrasound was used to disperse a biphasic mixture of CO2/H2O in a 1 dm3 high-pressure reactor at 30 °C/80 bar. A view cell positioned in-line with the sonic vessel allowed observation of a turbid emulsion which lasted approximately 30 min after ceasing sonication. Within the ultrasound reactor, simultaneous CO2-continuous and H2O-continuous environments were identified. The hydrolysis of benzoyl chloride was employed to show that at similar power intensities, comparable initial rates (1.6 ± 0.3 × 10–3 s–1 at 95 W cm–2) were obtained with those reported for a 87 cm3 reactor (1.8 ± 0.2 × 10–3 s–1 at 105 W cm–2), demonstrating the conservation of the physical effects of ultrasound in high-pressure systems (emulsification induced by the action of acoustic forces near an interface). A comparison of benzoyl chloride hydrolysis rates and benzaldehyde mass transport relative to the non-sonicated, ‘silent’ cases confirmed that the application of ultrasound achieved reaction rates which were over 200 times faster, by reducing the mass transport resistance between CO2 and H2O. The versatility of the system was further demonstrated by ultrasound-induced hydrolysis in the presence of the polysorbate surfactant, Tween, which formed a more uniform CO2/H2O emulsion that significantly increased benzoyl chloride hydrolysis rates. Finally, pulse rate was employed as a means of slowing down the rate of hydrolysis, further illustrating how ultrasound can be used as a valuable tool for controlling reactions in CO2/H2O solvent mixtures.Item Open Access A review of uncertainty in environmental risk: characterising potential natures, locations and levels(Taylor and Francis, 2013-06-10) Skinner, Daniel J. C.; Rocks, Sophie A.; Pollard, Simon J. T.Uncertainties, whether due to randomness or human or system errors, are inherent within any decision process. In order to improve the clarity and robustness of risk estimates and risk characterisations, environmental risk assessments (ERAs) should explicitly consider uncertainty. Typologies of uncertainty can help practitioners to understand and identify potential types of uncertainty within ERAs, but these tools are yet to be reviewed in earnest. Here, we have systematically reviewed 30 distinct typologies and the uncertainties they communicate and demonstrate that they: (1) use terminology that is often contradictory; (2) differ in the frequencies and dimensions of uncertainties that they include; (3) do not uniformly use systematic and robust methods to source information; and (4) cannot be applied, on an individual basis, to the domain of ERA. On the basis of these observations, we created a summary typology – consisting of seven locations (areas of occurrence) of uncertainty across five distinct levels (magnitude of uncertainty) – specifically for use with ERAs. This work highlights the potential for confusion, given the many versions of uncertainty typologies which exist for closely related risk domains and, through the summary typology, provides environmental risk analysts with information to form a solid foundation for uncertainty analysis (based on improved understanding) to identify uncertainties within an ERA.Item Open Access Evaluation of engineered nanoparticle toxic effect on wastewater microorganisms: current status and challenges(Elsevier, 2013-06-14) Eduok, Samuel; Martin, R.; Villa, Raffaella; Nocker, Andreas; Jefferson, Bruce; Coulon, FredericThe use of engineered nanoparticles (ENPs) in a wide range of products is associated with an increased concern for environmental safety due to their potential toxicological and adverse effects. ENPs exert antimicrobial properties through different mechanisms such as the formation of reactive oxygen species, disruption of physiological and metabolic processes. Although there are little empirical evidences on environmental fate and transport of ENPs, biosolids in wastewater most likely would be a sink for ENPs. However, there are still many uncertainties in relation to ENPs impact on the biological processes during wastewater treatment. This review provides an overview of the available data on the plausible effects of ENPs on AS and AD processes, two key biologically relevant environments for understanding ENPs–microbial interactions. It indicates that the impact of ENPs is not fully understood and few evidences suggest that ENPs could augment microbial-mediated processes such as AS and AD. Further to this, wastewater components can enhance or attenuate ENPs effects. Meanwhile it is still difficult to determine effective doses and establish toxicological guidelines, which is in part due to variable wastewater composition and inadequacy of current analytical procedures. Challenges associated with toxicity evaluation and data interpretation highlight areas in need for further research studies.