Browsing by Author "Trinh, Giang"

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    Microwave energy assisted synthesis of poly lactic acid via continuous reactive extrusion: modelling of reaction kinetics
    (Royal Society of Chemistry, 2017-03-27) Dubey, Satya P.; Abhyankar, Hrushikesh; Marchante, Veronica; Brighton, James L.; Bergmann, Björn; Trinh, Giang; David, Chantal
    The most commonly used batch process to manufacture PLA is ring opening polymerization (ROP) of lactide monomer in a suitable solvent, in the presence of a metallic/bimetallic catalyst (Sn, Zn, and Al) or other organic catalysts. However, this process does not lend itself to safer/cleaner and high throughput (and high volume) manufacturing. Continuous reactive extrusion of lactide monomer using a suitable reaction input has the potential to increase the throughput, and this route has been explored in the literature. In this work, reactive extrusion experiments using stannous octoate Sn(Oct)2 and tri-phenyl phosphine (PPh)3, were considered to perform ROP of lactide monomer using the microwave as an alternative energy (AE) source for activating and/or boosting the polymerization. Implementation of a microwave generator in a section of the extruder is one of the novelties of this research. A simulation model of ROP of PLA was formulated to estimate the impact of reaction kinetics and AE source on the polymerization process. Ludovic® software was used for the simulation of continuous reactive extrusion of the process. Experimental and simulated results were compared for the validation of the methodology. This work also highlights the advantages and drawbacks of most conventional metal catalysts, the effect of alternative energies on reaction mechanism, and safe and efficient production of PLA.
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    Modelling and validation of synthesis of poly lactic acid using an alternative energy source through a continuous reactive extrusion process
    (MDPI, 2016-04-22) Dubey, Satya P.; Abhyankar, Hrushikesh; Marchante, Veronica; Brighton, James L.; Blackburn, Kim; Temple, Clive; Bergmann, Björn; Trinh, Giang; David, Chantal
    PLA is one of the most promising bio-compostable and bio-degradable thermoplastic polymers made from renewable sources. PLA is generally produced by ring opening polymerization (ROP) of lactide using the metallic/bimetallic catalyst (Sn, Zn, and Al) or other organic catalysts in a suitable solvent. In this work, reactive extrusion experiments using stannous octoate Sn(Oct)2 and tri-phenyl phosphine (PPh)3 were considered to perform ROP of lactide. Ultrasound energy source was used for activating and/or boosting the polymerization as an alternative energy (AE) source. Ludovic® software, designed for simulation of the extrusion process, had to be modified in order to simulate the reactive extrusion of lactide and for the application of an AE source in an extruder. A mathematical model for the ROP of lactide reaction was developed to estimate the kinetics of the polymerization process. The isothermal curves generated through this model were then used by Ludovic software to simulate the “reactive” extrusion process of ROP of lactide. Results from the experiments and simulations were compared to validate the simulation methodology. It was observed that the application of an AE source boosts the polymerization of lactide monomers. However, it was also observed that the predicted residence time was shorter than the experimental one. There is potentially a case for reducing the residence time distribution (RTD) in Ludovic® due to the ‘liquid’ monomer flow in the extruder. Although this change in parameters resulted in validation of the simulation, it was concluded that further research is needed to validate this assumption.