Browsing by Author "Longhurst, Philip J."
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Item Open Access Ammonia inhibition and toxicity in anaerobic digestion: a critical review(Elsevier, 2019-12) Jiang, Ying; McAdam, Ewan; Zhang, Yue; Heaven, Sonia; Banks, Charles J.; Longhurst, Philip J.As a waste management technology which offers environmental benefit and renewable energy production, anaerobic digestion (AD) has become the preferred technology for the treatment of organic waste. However, in such waste streams nitrogen contents are likely to be high. There is prevailing literature evidence suggests that high ammonia concentration especially its free molecular form (NH3), derived from nitrogen content in substrates is the cause of inhibition and sudden failure of the AD process. This paper comprehensively reviews previous knowledge from digestion studies using high nitrogen waste streams as feedstocks and critically analysed the considerable variations in the inhibition/toxicity levels reported for ammonia. Literature evidences suggest methanogens, particularly acetoclastic methanogens are most susceptible to ammonia toxicity, and therefore this review has a particular focus on the mechanism of the ‘selective’ inhibition to methanogens and the impact of ammonia toxicity to the overall methanogen population in an AD digester. This population change explains in many reported cases that sufficient acclimatisation can significantly alleviate the phenomenon of inhibition and specific requirement of certain trace nutrients. Currently available mitigation strategies for high nitrogen content feedstock digestion are reviewed and discussed in relation to the population change and trace nutrient requirements.Item Embargo Analysis of factors driving foreign direct investment in the liquefied natural gas sector: case study Nigeria(Cranfield University, 2024-02) Ogunsanwo, Babafemi; Longhurst, Philip J.; Huo, DaThe empirical data revealed facts about factors driving foreign direct investment in the Nigerian LNG sector. This research uses the primary data gathered to contribute uniquely to empirical findings and knowledge. Some factors are deemed adequate when attracting foreign direct investment. The sufficient factors identified are political stability having a considerable impact on investor decisions, and long-term investment commitments in the LNG sector. The second significant factor identified is government efficiency, and the last factor is corruption with different components classified into two broad categories: attractors and deterrents. In this context, sufficiency is defined as the condition where FDI is likely to occur when a sufficient amount of the three factors listed are in place. Previous research has failed to understand and explain all three factors adequately. This is a new insight and contribution to knowledge. This study explains how factors driving foreign direct investment in Nigeria's liquefied natural gas sector have an impact. The research utilises the successful Bonny NLNG projects as an example to investigate the reasons behind the failure of the Olokola and Brass LNG projects, which were unable to reach a final investment decision. Distinct empirical analysis and research design show key factors driving foreign direct investment in the Nigerian LNG sector. Foreign direct investment is a type of cross-border investment that occurs when an investor from one country develops a long-term stake in and a considerable degree of control over an enterprise located in another country. Additionally, in green-field investment, foreign direct investment is in the form of a parent company establishing a subsidiary in another country and commencing operations from the ground up. The goal of foreign direct investment is the priority of gaining benefits from the investment, maximising return on investment, and seeking to control assets. It offers capital funding in exchange for an equity stake. LNG projects are capital- intensive, it requires sizable up-front financing. LNG project financing can be difficult due to their long-term nature, high costs, and associated risks. Securing funds from foreign lenders, equity investors, and project sponsors can be herculean, only the major exploration and production companies can achieve it. Thus, the research will focus on factors driving FDI in the LNG sector. Key stakeholders, policymakers, and investors will be interviewed. This thesis compiles feedback from stakeholders to identify the key factors driving foreign direct investment in Nigerian liquefied natural gas. The study presents evidence on the factors driving the inflow of foreign direct investment into the Nigerian LNG sector to policymakers, lawmakers, government executives, investors, community leaders, and financial institutions to test the effectiveness and efficiency of the research. The research design incorporates a mixed-method approach. Data collected through a questionnaire-based survey, semi-structured interviews, and focus group discussions, provide solid insight into the factors driving foreign direct investment in the Nigerian LNG sector. The questionnaire-based survey was used to gather data from 118 respondents. Data was gathered from 12 top gas stakeholders through semi-structured interviews, and an additional 4 executive participants participated in the focus group discussion. The study employs purposive sampling to identify the participants and interviewees. The fundamental value of the research comes from the real-world data it collects and the conclusions by looking at factors driving FDI in the LNG sector. Stakeholder theories were chosen as the theoretical framework for the research, emphasising the study's focus and applying the researcher's terminology to address the research questions. The literature review guided this decision. Nigeria's abundance of natural resources, particularly its substantial natural gas reserves, attracts foreign investors. The Nigerian gas sector presents opportunities for economic development, energy diversification, and environmental sustainability in the future. Nigeria has about nine hundred times more gas assets than the country's oil deposits, and its reputation as an oil producer overshadowed the gas sector's potential, even though the country's gas reserves are greater than oil. Gas asset is a necessary factor, but it is not sufficient enough to attract foreign direct investment.Item Open Access The application of a new research and development project selection model in SMEs.(Elsevier Science B.V., Amsterdam., 2006-02-01T00:00:00Z) Lawson, Craig P.; Longhurst, Philip J.; Ivey, Paul C.The work reported in this paper investigates Research and Development (R&D) project selection models, focusing on the application of a new hybrid project selection model in a UK based engineering Small to Medium-sized Enterprise (SME). Work is done to enable the new project selection model to be applied in an SME and the model is then field tested. Field test results provide insight into the barriers to the adoption of such a model in an SME, either as a decision support tool or as a knowledge acquisition and learning tool. Insights are gained into the suitability and limits that exist within SMEs for the use of such decision support models. As an outcome of the field test results a simple R&D project portfolio cash-flow tracking method is proposed.Item Open Access Application of machine learning in assessment of combustion of liquified natural gas.(Cranfield University, 2021-05) Alexandropoulos, Christos Dimosthenis; Hanak, Dawid P.; Longhurst, Philip J.This work focuses on the implementation on carbon capture on ships which run on liquified natural gas (LNG). LNG ships present a real-world example of LNG as well as a study case for carbon capture on LNG combustion. There is also special interest for that as well, since the International Maritime Organization (IMO), imposed a limit of 0.5% wt. of sulphur content in ship fuel has been imposed from 2020 to reduce pollution emissions from global shipping activities. This initiative will lead to major changes since the previous limit was set at 3.5% wt., which broadened fuel options for ships. In addition, the IMO is developing a long-term plan to completely nullify shipping’s impact on CO₂ emissions by 2030. Consequently, stricter regulations will be imposed to marine activities worldwide. LNG fuel seems to be a promising solution. The sulphur emissions are lower, in compliance with the latest IMO regulations. Additionally, it has a greater energy density in comparison to traditional fuels, like heavy fuel oil (HFO). This paper aims to study the feasibility of a project, which equips an LNG fuelled ship with a carbon capture system. The study includes an examination of an on-board carbon capture system, by simulating the LNG engine as well as the carbon capture system in simulation software. The engine model chosen is the Wärtsilä 6L34DF. The results of these simulations are analysed to examine the correlation between the system’s variables and to evaluate the possibility of heat integration within the system. The economic feasibility of the project is then assessed, using economic data. The results show that heat integration is possible. For example, the heat provided from the flue gas is calculated at 1.323MW when the reboiler duty is 0.3353 MW. However, the project is not sustainable under current market conditions.Item Open Access Appraisal for options of solid recovered fuel (SRF) utilisation within the UK(2006-11-29T00:00:00Z) Hill, D.; Garg, A.; Smith, Richard; Pollard, Simon J. T.; Longhurst, Philip J.In view of the rising prices of non-renewable fossil fuels and regulatory obligations affecting waste management, interest is growing for the use of waste derived fuels in energy intensive facilities in Europe. However, major concerns with the use of such fuels include the quality of fuels, its source of generation, gaseous emissions and public acceptability. This paper presents the various production methods for solid recovered fuels (SRF) from municipal solid waste (MSW) and the potential options for its use in the UK. SRF can be produced by mechanical biological treatment (MBT) methods using bio-drying process or by extensive mechanical treatment. MBT involves a series of mechanical and biological steps, depending upon the input waste properties, aimed at producing an SRF. SRF compositions vary according to the application and can comprise of paper, plastic, wood, textile and organics. The European Technical Committee CEN/TC 343 “Solid Recovered Fuels” classifies SRF on the basis of net calorific value (NCV), chlorine content and mercury content. This classification system was prepared after extensive consultation with end-users. In the UK, the main potential outlets for MSW derived SRF include cement kilns, power plants, industrial boilers (such as pulp and paper mill), dedicated SRF incineration facilities and advanced thermal treatment plants (such as gasification and Venice 2006: Biomass and Waste to Energy Symposium. Cini Foundation, Venice, Italy. 29 November – 1 December 2006. pyrolysis). Cement kiln operators prefer high NCV fuel, however, in spite of its lower CV in comparison to other waste derived fuels (like liquid solvents, tyres and MBM), it remains attractive due to its biomass fraction and cheap availability. Power plants are much more concerned with the biomass fraction, as it may bring revenues for them in the form of Renewable Obligation Certificates (ROCs). Similarly, gasification and pyrolysis techniques are also eligible for ROCs, but these are still not fully proven in the UK. The use of SRF is also of interest because of its potential to reduce greenhouse gas emissions, as the biomass rich fraction is considered ‘carbon neutral’. Thus, this assists energy facilities to meet the EU Emissions Trading Scheme targets. However, the application of SRF is not straightforward as legislation exists at EU and National level, which users need to comply with. In addition, technical, environmental and economic issues need to be addressed. On the other hand if more SRF can be used then this will greatly help the UK meet its obligations under the Landfill Directive and the mitigation of greenhouse gases.Item Open Access Appropriateness of selecting different averaging times for modelling chronic and acute exposure to environmental odours(Elsevier, 2007-04-01T00:00:00Z) Drew, Gillian H.; Smith, Richard; Gerard, Valerie; Burge, C.; Lowe, M.; Kinnersley, Robert P.; Sneath, Robert W.; Longhurst, Philip J.Odour emissions are episodic, characterised by periods of high emission rates, interspersed with periods of low emissions. It is frequently the short term, high concentration peaks that result in annoyance in the surrounding population. Dispersion modelling is accepted as a useful tool for odour impact assessment, and two approaches can be adopted. The first approach of modelling the hourly average concentration can underestimate total odour concentration peaks, resulting in annoyance and complaints. The second modelling approach involves the use of short averaging times. This study assesses the appropriateness of using different averaging times to model the dispersion of odour from a landfill site. We also examine perception of odour in the community in conjunction with the modelled odour dispersal, by using community monitors to record incidents of odour. The results show that with the shorter averaging times, the modelled pattern of dispersal reflects the pattern of observed odour incidents recorded in the community monitoring database, with the modelled odour dispersing further in a north easterly direction. Therefore, the current regulatory method of dispersion modelling, using hourly averaging times, is less successful at capturing peak concentrations, and does not capture the pattern of odour emission as indicated by the community monitoring database. The use of short averaging times is therefore of greater value in predicting the likely nuisance impact of an odour source and in framing appropriate regulatory controls.Item Open Access Arsenic transformation behaviour during thermal decomposition of P. vittata, an arsenic hyperaccumulator(Elsevier, 2017-01-22) Duan, Lunbo; Li, Xiaole; Jiang, Ying; Lei, Mei; Dong, Ziping; Longhurst, Philip J.Thermal treatment of P. vittata, an arsenic hyperaccumulator harvested from contaminated land is a promising method of achieving volume reduction, energy production and arsenic (As) recovery simultaneously. In this paper, the arsenic transformation characteristics of field-harvested P. vittata were investigated during its pyrolysis and gasification process. The produced solid residue and flue gas were analysed by a high performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) to determine both the arsenic concentration and speciation. Moreover, the occurrence of arsenic in the solid residues was further identified as soluble and insoluble, which can feed information to the next arsenic recovery step. Results show that the fuel arsenic into gas phase increases firstly from 400 °C to 600 °C, but then drops from 600 °C to 800 °C, probably due to the self-retention of arsenic by CaO enriched in this P. vittata. Further increasing temperature to 900 °C will result in fast arsenic release. Gasification results in slightly higher arsenic release into the gas phase compared with pyrolysisItem Open Access Assessing the perception and reality of arguments against thermal waste treatment plants in terms of property prices(Elsevier, 2013-09-21) Philips, K. J. O.; Longhurst, Philip J.; Wagland, Stuart ThomasThe thermal processing of waste materials, although considered to be an essential part of waste management, is often sharply contested in the UK. Arguments such as health, depletion of resources, cost, noise, odours, traffic movement and house prices are often cited as reasons against the development of such facilities. This study aims to review the arguments and identify any effect on property prices due to the public perception of the plant. A selection of existing energy from waste (EfW) facilities in the UK, operational for at least 7 years, was selected and property sales data, within 5 km of the sites, was acquired and analysed in detail. The locations of the properties were calculated in relation to the plant using GIS software (ArcGIS) and the distances split into 5 zones ranging from 0 to 5 km from the site. The local property sale prices, normalised against the local house price index, were compared in two time periods, before and after the facility became operational, across each of the 5 zones. In all cases analysed no significant negative effect was observed on property prices at any distance within 5 km from a modern operational incinerator. This indicated that the perceived negative effect of the thermal processing of waste on local property values is negligible.Item Open Access An assessment of different extraction and quantification methods of penta- and hexa-chlorobenzene from SRF fly-ash(Elsevier, 2017-01-26) Balampanis, Dimitris E.; Coulon, Frederic; Simms, Nigel; Longhurst, Philip J.; Pollard, Simon J. T.; Fenech, Cecilia; Villa, RaffaellaHighly chlorinated benzenes, produced in the presence of organic matter and chlorine, are considered PCDD/Fs precursors, and are used as cost and time convenient substitute indicators for the indirect measurement of the latter. In this study penta- and hexa-chlorobenzene are quantified for the determination of the organochloride load of fly ash from solid recovered fuel incineration. Some of the chlorobenzenes are formed under ‘de novo’ conditions, through heterogeneous (ash particles/flue gases) reactions and are therefore deeply incorporated within fly ash. Accelerated solvent extraction (ASE) and ultrasonic solvent extraction (USE), along with the equivalent clean-up methods suggested by literature were compared to traditional Soxhlet. The extraction efficiencies achieved were 83 ± 7.5% for Soxhlet, 111 ± 19% for PFE, and 67 ± 17% for ultrasonication. Soxhlet extraction and clean-up through a multilayer silica gel column gave more precise results compared to the other sample preparation methods. Furthermore, performance comparison of gas chromatography fitted with either a mass spectrometer operated in single ion monitoring mode (GC-MS-SIM), or electron capture detector (GC- ECD) highlighted that ECD can be used for measuring chlorobenzenes traces down to 0.21 ng g−1, when the equivalent LOQ for MS-SIM was 3.26 ng g−1. The results further suggest that ECD can provide better peak integration than MS-SIM in the detection of chlorobenzenes in fly ash extracts, due to the detector's sensitivity to halogenated compounds.Item Open Access Assessment of municipal waste compost as a daily cover material for odour control at landfill sites.(Elsevier Science B.V., Amsterdam., 2005-01-01T00:00:00Z) Hurst, C.; Longhurst, Philip J.; Pollard, Simon J. T.; Smith, Richard; Jefferson, Bruce; Gronow, Jan R.The ability of municipal waste compost as a daily cover material to reduce the odorous emissions associated with landfill surfaces was investigated. Trials were carried out using landfill gas, a certified sulphurous gas mix and ambient air as a control. Odorous gas was passed through portable test column filled with compost at different densities (590 kg/m3 and 740 kg/m3). Gas samples were taken from the inlet, outlet and at varying column depths and examined using a combination of sensory analysis (olfactometry) and a novel analytical method (Transportable Selected Ion Flow Tube – TSIFT). Results for the trials using landfill gas showed a 69% odour reduction (OU/m3) through the column for compost with a bulk density of 590 kg/m3, and a reduction of 97% using compost with a bulk density of 740 kg/m3. TSIFT analysis showed an overall decrease in the concentration of terpenes, and sulphurous compounds in the outlet gas from the column for both bulk densities. No significant trend could be identified for the concentrations at different depths within the column. Results show the ability of compost to reduce landfill odours under differing conditions. The inconclusive data provided by TSIFT analysis may be due to the analysis of compounds that are not contributing to odour, and thus highlights the potential for synergetic effects and the importance of sensory measurement when examining odorous emissionItem Open Access Bioaerosol release from composting facilities(Cranfield University, 2005-10) Mohamed Taha, M. P. B; Pollard, Simon J. T.; Longhurst, Philip J.The use of composting is expected to increase dramatically due to its economic and environmental benefits. For public health protection, regulators and licensing authorities are requesting risk assessments to be conducted prior to the development and operation of composting. Significant amounts of microrganisms can be aerosolised and transported by winds to points of exposure. However, the source term factors that influence their release and their dispersal are not fully understood. In this thesis a method to measure viable bioaerosols emission rates from static compost pile surfaces and during the agitation of compost was developed. The factors that influence the emission of bioaerosols from compost piles of different ages and during different agitation activities were evaluated. A wind tunnel analysis was successfully used to measure the surface flux bioaerosols emission rate. Newly estimated emission rates from various source terms were then modelled to produce source depletion curves. The surface emission flux of a static pile was estimated to be 102 to 104cfu/m2/s for both A. fumigatus and actinomycetes. The turning of compost releases the highest bioaerosols concentration range from 104 to 108cfu/s compared with the shredding and screening. The turning of an early stage compost windrow emitted the highest amount of bioaerosols. This study introduces a new method for quantifying bioaerosols dispersal, thus improving the risk assessments required for environmental permitting.Item Open Access Biodrying for mechanical-biological treatment of wastes: A review of process science and engineering(Elsevier Science B.V., Amsterdam., 2009-06-01T00:00:00Z) Velis, C. A.; Longhurst, Philip J.; Drew, Gillian H.; Smith, Richard; Pollard, Simon J. T.Biodrying is a variation of aerobic decomposition, used within mechanical–biological treatment (MBT) plants to dry and partially stabilise residual municipal waste. Biodrying MBT plants can produce a high quality solid recovered fuel (SRF), high in biomass content. Here, process objectives, operating principles, reactor designs, parameters for process monitoring and control, and their effect on biodried output quality are critically examined. Within the biodrying reactors, waste is dried by air convection, the necessary heat provided by exothermic decomposition of the readily decomposable waste fraction. Biodrying is distinct from composting in attempting to dry and preserve most of biomass content of the waste matrix, rather than fully stabilise it. Commercial process cycles are completed within 7–15 days, with mostly H2O(g) and CO2 loses of ca. 25–30% w/w, leading to moisture contents of <20% w/w. High airflow rate and dehumidifying of re-circulated process air provides for effective drying. We anticipate this review will be of value to MBT process operators, regulators and end-users oItem Open Access The biogenic content of process streams from mechanical-biological treatment plants producing solid recovered fuel. Do the manual sorting and selective dissolution determination methods correlate?(Elsevier Science B.V., Amsterdam., 2010-07-31T00:00:00Z) Severin, M.; Velis, C. A.; Longhurst, Philip J.; Pollard, Simon J. T.The carbon emissions trading market has created a need for standard methods for the determination of biogenic content (chi(B)) in solid recovered fuels (SRF). We compare the manual sorting (MSM) and selective dissolution methods (SDM), as amended by recent research, for a range of process streams from a mechanical biological treatment (MBT) plant. The two methods provide statistically different biogenic content values, as expressed on a dry mass basis, uncorrected for ash content. However, they correlate well (r(2) > 0.9) and the relative difference between them was <5% for chi(B) between 21% (w)/W-d and 72% (w)/W-d (uncorrected for ash content). This range includes the average SRF biogenic content of ca. 68% (w)/W-d. Methodological improvements are discussed in light of recent studies. The repeatability of the SDM is characterised by relative standard deviations on triplicates of <2.5% for the studied population. (C) 2010 Elsevier Ltd. All rights reserved.Item Open Access Biomass resources and biofuels potential for the production of transportation fuels in Nigeria(Elsevier, 2016-05-26) Longhurst, Philip J.; Ben-Iwo, Juliet; Manovic, VasilijeSolid biomass and waste are major sources of energy. They account for about 80% of total primary energy consumed in Nigeria. This paper assesses the biomass resources (agricultural, forest, urban, and other wastes) available in Nigeria and the potential for biofuel production from first, second, third and fourth generation biomass feedstocks. It reviews the scope of biomass conversion technologies tested within the country and the reports on the technology readiness level of each. Currently, most of the emerging biofuels projects in Nigeria utilize first generation biomass feedstock for biofuel production and are typically located many miles away from the petroleum refineries infrastructures. These feedstocks are predominantly food crops and thus in competition with food production. With significant availability of non-food biomass resources, particularly in the Niger Delta region of Nigeria, and the petroleum refineries located in the same area, it is pertinent to consider expanding use of the petroleum refinery׳s infrastructure to co-process non-food biomass into bio-intermediate oil for blending with petroleum. This not only addresses the potential food versus fuel conflict challenging biofuel production in Nigeria, but also reduces the cost of setting up new bio-refineries thus eliminating the transportation of ethanol to existing petroleum refineries for blending. In view of this, it is recommended that further research be carried out to assess the feasibility of upgrading existing refineries in Nigeria to co-process bio-based fuels and petroleum products thus achieving the targets set by the Nigeria Energy Commission for biofuel production in the country.Item Open Access The Capability of Design in Government(2020-03) Geraghty, Rhonda Nadine; Longhurst, Philip J.; Encinas-Oropesa, AdrianaThis research increases understanding of the scope and potential of design as resource in the context of government. Currently, there is limited knowledge and use of tangible and intangible dimensions of design in government and its potential remains unrealized. This despite designs established history of use, evidence to support its economic, social, environmental, and political value and encouragement from national and international bodies. What design is and its capacity to contribute in government is explored in this research. Accomplished through seven phases of investigations, the design-in- government context is first established and then explored followed by an examination of what design is and does within this context. A mixed methods approach was employed involving a critical assessment of both theoretical and empirical insights, including a scoping review, a focused review of literature, interviews with practitioners and primary and secondary observations of the design-in-government phenomena in practice. Interactions with stakeholders, academia and industry at international engagements informed the research process and evaluated study results incrementally over a 6-year period from 2013-2019. Results reveal a dimensional and holistic perspective of design as capability in operation within a dynamic design-in-government system. Here the potential exists for all facets of design to impact all areas of government simultaneously. The establishment of the design-in-government conceptual framework and definition of design for this context are also significant outcomes from this study. Together they constitute constructs that contribute to the furtherance of the novel field of research and practice with implications for design education and the evolving design profession. Finally, the distinctive scoping review process from this research contributes to the theoretical advancement of the methodology.Item Open Access Carbon Brainprint Case Study: training for landfill gas inspectors(2011-07-31T00:00:00Z) Parsons, David J.; Chatterton, Julia C.; Longhurst, Philip J.Anaerobic deterioration of biodegradable wastes in landfill sites is an important source ofgreenhouse gases. Of the estimated UK total of 2330 kt methane emitted in 2008, 966 kt(equivalent to 24 Mt of carbon dioxide) came from landfill, compared with 876 kt from livestockagriculture, the next largest source. Increasing the amount of methane that is recovered andused as fuel is an important method of reducing emissions. In 2008 Cranfield University was asked by the Environment Agency (EA) to run a 12 day course to train 12 EA officers, based on the knowledge of a retired EA industry expert. At the end of thecourse, the students split into two groups, each of which undertook 12 site visits. These 24sites were subsequently assessed by the EA, who estimated that the additional measuresrecommended had collected an additional 7,600 m3/hr of landfill gas. A further 12 officers havenow received the advanced training, and another 70 have attended a foundation course inwhich they learn how to audit and assess landfill gas controls on sites. The additional collection of methane resulting from the first set of visits is equivalent to453 kt CO2e/year. Extrapolating from this by making conservative assumptions about possiblediminishing returns, the savings to the end of 2010 from the two groups (the retrospectivebrainprint) are about 1,330 kt CO2e with a 95% confidence range of 1,091-1,570 kt CO2e. Usingthe same assumptions, if both groups continue working for a further three years, the savingsover the five year period (the prospective brainprint) will be 5,380 kt CO2e with a 95%confidence range of 3,695-7,309 kt CO2e.Item Open Access Carbon brainprint – An estimate of the intellectual contribution of research institutions to reducing greenhouse gas emissions(Elsevier, 2015-05-07) Chatteron, Julia C.; Parsons, David J.; Nicholls, John R.; Longhurst, Philip J.; Bernon, Mike; Palmer, Andrew; Brennan, Feargal P.; Kolios, Athanasios; Wilson, Ian; Ishiyama, Edward; Clements-Croome, Derek; Elmualim, Abbas; Darby, Howard; Yearly, Tom; Davies, Gareth J.Research and innovation have considerable, currently unquantified potential to reduce greenhouse gas emissions by, for example, increasing energy efficiency. Furthermore, the process of knowledge transfer in itself can have a significant impact on reducing emissions, by promoting awareness and behavioural change. The concept of the ‘carbon brainprint’ was proposed to convey the intellectual contribution of higher education institutions to the reduction of greenhouse gas emissions by other parties through research and teaching/training activities. This paper describes an investigation of the feasibility of quantifying the carbon brainprint, through six case studies. The potential brainprint of higher education institutes is shown to be significant: up to 500 kt CO2e/year for one project. The most difficult aspect is attributing the brainprint among multiple participants in joint projects.Item Open Access CFD modelling of particle shrinkage in a fluidized bed for biomass fast pyrolysis with quadrature method of moment(Elsevier, 2017-05-08) Liu, Bo; Papadikis, Konstantinos; Gu, Sai; Fidalgo, Beatriz; Longhurst, Philip J.; Li, Zhongyuan; Kolios, AthanasiosAn Eulerian-Eulerian multi-phase CFD model was set up to simulate a lab-scale fluidized bed reactor for the fast pyrolysis of biomass. Biomass particles and the bed material (sand) were considered to be particulate phases and modelled using the kinetic theory of granular flow. A global, multi-stage chemical kinetic mechanism was integrated into the main framework of the CFD model and employed to account for the process of biomass devolatilization. A 3-parameter shrinkage model was used to describe the variation in particle size due to biomass decomposition. This particle shrinkage model was then used in combination with a quadrature method of moment (QMOM) to solve the particle population balance equation (PBE). The evolution of biomass particle size in the fluidized bed was obtained for several different patterns of particle shrinkage, which were represented by different values of shrinkage factors. In addition, pore formation inside the biomass particle was simulated for these shrinkage patterns, and thus, the density variation of biomass particles is taken into account.Item Open Access China's soil and groundwater management challenges: Lessons from the UK's experience and opportunities for China(Elseveir, 2016-03-10) Coulon, Frederic; Jones, Kevin; Li, Hong; Hu, Qing; Gao, Jingyang; Li, Fasheng; Chen, Mengfang; Zhu, Yong-Guan; Liu, Rongxia; Liu, Ming; Canning, Kate; Harries, Nicola; Bardos, Paul; Nathanail, C. Paul; Sweeney, Rob; Middleton, David; Charnley, Maggie; Randall, Jeremy; Richell, Martin; Howard, Trevor; Martin, Ian; Spooner, Simon; Weeks, Jason; Cave, Mark; Yu, Fang; Zhang, Fang; Jiang, Ying; Longhurst, Philip J.; Prpich, George; Bewley, Richard; Abra, Jonathan; Pollard, Simon J. T.There are a number of specific opportunities for UK and China to work together on contaminated land management issues as China lacks comprehensive and systematic planning for sustainable risk based land management, encompassing both contaminated soil and groundwater and recycling and reuse of soil. It also lacks comprehensive risk assessment systems, structures to support risk management decision making, processes for verification of remediation outcome, systems for record keeping and preservation and integration of contamination issues into land use planning, along with procedures for ensuring effective health and safety considerations during remediation projects, and effective evaluation of costs versus benefits and overall sustainability. A consequence of the absence of these overarching frameworks has been that remediation takes place on an ad hoc basis. At a specific site management level, China lacks capabilities in site investigation and consequent risk assessment systems, in particular related to conceptual modelling and risk evaluation. There is also a lack of shared experience of practical deployment of remediation technologies in China, analogous to the situation before the establishment of the independent, non-profit organisation CL:AIRE (Contaminated Land: Applications In Real Environments) in 1999 in the UK. Many local technology developments are at lab-scale or pilot-scale stage without being widely put into use. Therefore, a shared endeavour is needed to promote the development of technically and scientifically sound land management as well as soil and human health protection to improve the sustainability of the rapid urbanisation in China.Item Open Access Comparative evaluation of SRF and RDF co-combustion with coal in a fluidised bed combustor(2007-10-01T00:00:00Z) Garg, A.; Smith, Richard; Longhurst, Philip J.; Pollard, Simon J. T.; Simms, Nigel J.; Hill, D.The experimental study reported here was carried out to assess the feasibility of municipal solid waste (MSW) derived solid recovered fuel (SRF) in energy recovery applications. SRF was prepared by grinding and blending the major MSW constituents such as paper, plastics, wood and textile. The percentage of various constituents was the same as from the Ecodeco process employing bio- drying followed by mechanical treatment. The heating value of synthetic SRF was ca. 21 MJ/kg (as received basis). The metal emission results from the SRF co- combustion with coal were compared with that obtained from coal mono-combustion and refuse derived fuel (RDF) co-combustion with coal. RDF was also derived from MSW and was obtained from a local mechanical treatment waste facility. Use of SRF as co-fuel does not increase the emissions of metals to the environment in the flue gas stream when compared to coal mono-combustion. In addition, use of MSW derived fuel reduces the arsenic release to the atmosphere. The results showed that most of the metals are retained in the ash components (except mercury). The mobility of metals depends on the volatility and type of feedstock.