Browsing by Author "Longhurst, Phil"
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Item Open Access Deep learning in material recovery: Development of method to create training database(Elsevier, 2019-02-05) Vrancken, Carlos; Longhurst, Phil; Wagland, StuartIncreasing the rate of material identification, separation and recovery is a priority in resource management and recovery, and rapid, low cost imaging and interpretation is key. This study uses different combinations of cameras, illuminations and data augmentation techniques to create databases of images to train deep neural networks for the recognition of fibre materials. Using a limited set of 24 material samples sized 1200 cm2, it compares the outcome of reducing them to 30 cm2. The best classification accuracies obtained range from 76.6% to 77.5% indicating it is possible to overcome problems such as limited available materials, time, or storage capabilities, by using a setup with 5 cameras, 5 lights and applying simple software image manipulation techniques. The same method can be used to create deep neural network training databases to recognise a wider range of materials typically found in solid waste streams, in real-time. Furthermore, it offers flexibility as the classification cameras could be deployed at different stages within solid waste processing plants, providing feedback for process control, with the potential of increasing plant efficiency and reducing costs.Item Open Access Explaining the green development behavior of local governments for sustainable development: evidence from China(MDPI, 2023-10-01) Du, Jianguo; Zhu, Xiaowen; Li, Xingwei; Ünal, Enes; Longhurst, PhilAlthough researchers have examined organizational sustainability practices, a specific interpretation of local government green development practices remains for supplemental analysis. This study conducted an empirical survey of 53 local officials from departments related to green development to understand the key processes and practices of green development behavior of local governments in China. The key findings indicate that the main stakeholders involved in the green development practices of Chinese local governments consist of enterprises and residents. In part, local government green development practices emphasize the greening of enterprises, especially in the step of process environmental regulation. The new institutionalism theory and the organizational process research provide dependable insights into green development behaviors. Our findings further shed light on the process of cross-sectoral cooperation across local government departments in green development, contributing to local multi-sectoral interactions for regional green development.Item Open Access Fabrication of agave tequilana bagasse/PLA composite and preliminary mechanical properties assessment(Elsevier, 2020-05-15) Huerta-Cardoso, Omar; Durazo-Cardenas, Isidro; Longhurst, Phil; Simms, Nigel J.; Encinas-Oropesa, AdrianaBagasse agave tequilana fibres (ATF), an abundant by-product of Mexican tequila production, were characterised, treated and investigated as a reinforcement and filler material for polylactic acid (PLA) green composites. Two fibre pre-treatments were investigated: alkali (8% NaOH solution) and enzymatic (0.4% Pectate lyase solution). Composites pellets of 20, 40 and 60% (w/v) of ATF in PLA were manufactured using extrusion moulding. Press moulding was used to fabricate samples composite plates. Tensile, flexural, impact and water absorption properties were investigated on machined samples. Assessment of the mechanical properties showed tensile strength of up to 57.1 MPa for 20 % (w/v) of ATF untreated samples. Flexural strength up to 98.8 MPa and impact strength of 6.8 kJ/m2 for 40% (w/v) of ATF alkali treated samples. These values compare well with those of other new bio-composites. The values of the Young’s and flexural moduli are in proximity, if not superior, to those of widely used polymers PLA and GPPS. The optimal ATF loading was found to be ∼40%. Alkali treatment of fibres provided marginally improved mechanical properties; while significantly increasing the samples’ water absorption. Microscopy observations confirmed the two pre-treatments enhanced the fibre/matrix adhesion when compared with untreated fibres.Item Open Access Molecular structure characterization of bituminous coal in Northern China via XRD, Raman and FTIR spectroscopy(Elsevier, 2021-03-22) Jiang, Jingyu; Zhang, Shuo; Longhurst, Phil; Yang, Weihua; Zheng, ShaojieBituminous coal is used widely for a variety of applications despite causing a range of problems within processes. The complexity and heterogeneity of the molecular structure of coal is one of the reasons for problems during use. Investigation into the molecular structure of the bituminous coal is reported from using X-ray diffraction (XRD), Raman spectroscopy, and Fourier Transform infrared (FTIR) spectroscopy experiments on four coal samples from coal mines in Northern China. The average lateral sizes (La), stacking heights (Lc) and interlayer spacing (d002) of the coal samples’ crystallite structures derived from the XRD ranged from 25.78 to 27.93 Å, 17.27 to 25.88 Å and 3.40 to 3.52 Å, respectively; and the G-D1, ID1/IG and La of the samples ranged from 245.06 to 249.63 cm−1, 2.18 to 2.48 and 18.16 to 20.64 Å, respectively. The FTIR spectra reveals that coal samples incorporate oxygen-containing functional groups, aliphatic functional groups, aromatic functional groups and hydroxyl functional groups. Results show these four coal samples contained a low degree of ordered microcrystalline units with a low degree of aromatic conformation. The samples have the largest proportion of oxygenated functional groups, followed by aromatic structures, aliphatic structures and hydroxyl groups. Results from this study could inform the ongoing study of molecular structural characteristics of bituminous coal as well as help our understanding of properties such as wettability and pore structure.Item Open Access Promoting Sino-UK Collaboration on Developing Low Carbon and Sustainable Methodologies for Brownfields and Marginal Land Re-use in China(2017-01) Coulon, Frederic; Campo Moreno, Pablo; Jiang, Ying; Longhurst, Phil; Bardos, Paul; Li, Xiaonuo; Harries, Nicola; Jones, Kevin; Li, Hong; Li, Fasheng; Cao, Yunzhe; Hu, Qing; Gao, Jingyang; Chen, Mengfang; Zhu, Yong-Guan; Cai, ChaoRapid urbanisation and changes in land use resulting from industrial change has left a legacy of vast polluted industrial and commercial areas (also called brownfields) and marginal land areas. Recent evidence from the UK, EU and USA indicate that these land areas may have considerable potential for renewables production, for example from solar, wind or biomass. In parallel there are opportunities for carbon storage in rehabilitated soil, as well as substitution by the production of renewables. The UK is also leading the understanding in the wider parallel benefits that can be achieved from ecosystem services and public health benefits from improved provision of green space. These multiple services can be provided together, in synergy, from soft re-uses of post-industrial sites, and in this way the post-industrial regeneration areas in China should be seen as a major opportunity for new enterprise, society and the wider environment. The improving bankability of renewable energy projects, and the possibility of creating a voluntary carbon offset business, means that revenue streams may be sufficient to pay for ongoing land management over time as a profit generating activity. In terms of fastest benefit to UK PLC and China, the likelihood is that combination of renewable energies with “dual use” for habitat will provide both more readily commercial brownfield re-use opportunities for cities in China in the short term, and also create better carbon management opportunities, as well as a variety of wider sustainability benefits. Thus this type of re-uses will create a platform for rapid commercial exchange and development between Chinese and UK companies. Considering that China is preparing an action plan for managing soil pollution and remediation across the country estimated to be RMB 7tn which is equivalent to one-third of the national exchange reserves, this report on developing low carbon and sustainable methodologies for brownfields and marginal land re-use in China provides timely information that will support the decision making for sustainable remediation opportunities in China. The report is intended to serve as a tool and resource guide to stakeholders involved in land remediation willing to engage in sustainable remediation implementation for renewable energy and carbon management applications. It is intended to inform remediation stakeholders unfamiliar with sustainable remediation about the concept, practices, and available resources. The report capitalises on UK leadership positions on the sustainable rehabilitation of brownfields land (SURF-UK), the soft re-use of brownfields (e.g. for energy or amenity rather than buildings); effective end-use directed risk management for contaminated land, and sustainable remediation.Item Open Access Up-cycling of agave tequilana bagasse-fibres: A study on the effect of fibre-surface treatments on interfacial bonding and mechanical properties(Elsevier, 2020-11-18) Huerta-Cardoso, Omar; Durazo-Cardenas, Isidro; Marchante Rodriguez, Veronica; Longhurst, Phil; Coulon, FredericThe aim of this study was to assess the feasibility of upcycling fibre residues from the harvesting and production of tequila to green composites. Specifically, four different surface-modified natural fibres were assessed as raw material for green composite production. Before any surface treatment, the morphology and tensile properties of agave bagasse fibres from the tequila production batches were determined by optical and environmental scanning electron microscopy (ESEM) and single fibre tensile test, respectively. Further to this, agave fibres were exposed by immersion to four surface treatments including alkali, acetylation, enzymatic and silane treatments, in order to improve their morphology and compatibility with polylactic acid (PLA). The effects of these treatments on fibres’ morphology, mechanical properties (i.e. Youngs modulus and ultimate tensile strength), interfacial shear strength (IFSS), and water absorption were assessed. Overall, surface treatments showed improvements in agave bagasse fibre properties with the best results for alkali treated fibres with an ultimate tensile strength of 119.10 MPa, Young modulus of 3.05 GPa, and an IFSS of up to ~60% higher (5.21 MPa) to that performed by untreated samples. These tests allowed to identify alkali treatment as the most suitable for agave bagasse fibres. These results shed light on the interfacial interaction between agave bagasse fibres and PLA and the potential to up-cycle these residue agave fibres to manufacture PLA-based green composites.Item Open Access Using life cycle assessment in environmental engineering education(Taylor and Francis, 2019-06-10) Burnley, Stephen; Wagland, Stuart; Longhurst, PhilLife cycle assessment (LCA) is a method of assessing the environmental impacts of the manufacture and use of a product or provision of a service such as waste management. LCAs are based on quantitative science, but softer skills are also required in interpreting the results. Therefore, LCA provides an ideal opportunity for students to develop and apply both quantitative and qualitative skills in order to address complex real-world problems. In this research a simplified spreadsheet LCA tool was produced for students to assess the environmental impacts of a waste management system. Detailed feedback from face to face and distance-learning students were positive about the tool, with students welcoming the detail provided in the results and the use of a practical example to help their learning. In conclusion, LCA is an effective way of encouraging environmental and engineering students to develop and apply a wide range of transferable skills.