Browsing by Author "Liu, Hongtao"
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Item Open Access Dynamic evolution of humic acids during anaerobic digestion: exploring an effective auxiliary agent for heavy metal remediation(Elsevier, 2020-10-28) Wang, Xiqing; Lyu, Tao; Dong, Renjie; Liu, Hongtao; Wu, ShubiaoInformation on the dynamic evolution of humic acid (HA) from anaerobic digestate and the potential of HA serving as an effective agent for remedying heavy metals is rather scarce. This study monitored the evolution of the structure and functional groups and metal-binding abilities of HA during chicken manure and corn stover anaerobic digestion (AD) processes. Higher increases in aromatic (41-66%) and oxygen-containing functional groups (37-45%) were observed in HA from the AD of corn stover, resulting in higher metal-binding abilities for Cu(II), Co(II), and Ni(II) than those of chicken manure AD. Moreover, HA extracted from fast (before day 12 for chicken manure and day 16 for corn stover), and slow (day 40) methane production stages performed different complexation capacities for the heavy metals. These results reveal the mechanisms of HA and heavy metal interactions, and confirm the potential of HA extracted from AD process for the remediation of heavy metals.Item Open Access Mechanisms of genuine humic acid evolution and its dynamic interaction with methane production in anaerobic digestion processes(Elsevier, 2020-10-14) Wang, Xiqing; Muhmood, Atif; Lyu, Tao; Dong, Renjie; Liu, Hongtao; Wu, ShubiaoHumic acid (HA), a byproduct formed during the biological conversion of organic matter into biogas in the anaerobic digestion (AD) process, contains complex structures and redox functions. However, the evolution mechanism of HA and its interaction with CH4 production during the AD process have not been fully explored, particularly with respect to various substrates and temperature conditions. In this study, we investigated the evolutionary dynamics of the structure and function of genuine HA that naturally formed in the AD processes of chicken manure and corn stover under mesophilic (37 °C) and thermophilic (55 °C) conditions. The results demonstrated that the HA evolution mechanisms in AD of chicken manure and corn stover have different pathways. The AD of core stover showed higher degree of aromaticity (41.2–66.7% and 45.3–68.4% for mesophilic and thermophilic respectively) and humification index (1.5–4.2 and 2.8–4.5 for mesophilic and thermophilic respectively) than those (28.3–45.3% and 30.2–54.5% of aromaticity and 0.6–1.2 and 1.3–3.7 of humification index) in AD of chicken manure. The results from HSQC NMR spectroscopy and 2D-COS-FTIR spectroscopy demonstrated an accelerating effect of the higher temperature on the evolution of HA through humification. Moreover, the concurrent decomposition and re-polymerization of HA during both AD processes, resulting in positive and negative effects on CH4 production in the fast and slow CH4 production stages, respectively. The dynamic interaction was due to variations in the electron transferring ability and structure of the formed HA. The results could not only advance our understanding of the mechanisms of HA evolution and its interaction with the performance of AD process, but also support further research toward improving AD performance by regulating HA formation and transformation.Item Open Access Off-design thermodynamic performances of a combined solar tower and parabolic trough aided coal-fired power plant(Elsevier, 2020-10-13) Liu, Hongtao; Zhai, Rongrong; Patchigolla, Kumar; Turner, Peter J.; Yang, YongpingThe solar tower and parabolic trough aided coal-fired power generation has been demonstrated as a promising technology and has potential advantages in utilisation of solar energy in a cost-effective manner. Due to introduction of solar energy, from the solar tower or parabolic troughs, increases to a certain extent, the steam temperature would be difficult to maintain and leads to safety concerns. Therefore, the limitation of integrated solar energy, considering the overlapped influence of different solar energy input, needs to be well identified and managed. This work considered a 600 MWe integrated system as an example. Solar energy from parabolic troughs is used in the preheater while energy from the solar tower is used to reheat steam. The novelty of this study is the interaction of different solar energy input in fossil plants and its benefits is revealed for the first time. The maximum absorbed solar energy, considering the mutual effects of introduced solar energy flows, are explored. Then the system performance under three different loads (100%, 75%, 50%) and hourly operational performance in four typical days are analysed. The paper shows that the feed-water extraction results in the enhancement of maximum solar energy absorbed by reheat steam extraction, is improved by 24.2 MWth (28.5%), 11.5 MWth (20.0%), and 5.6 MWth (14.3%) as feed-water extraction percentages increase at the three load conditions. As a result, the minimum standard coal consumption rates are improved by 13.2 g/kWh (5.2%), 10.7 (4.1%) g/kWh and 9.0 g/kWh (3.1%) respectively. In four typical days, the highest coal consumption reduction is reached in the summer solstice, which is 266.6-tonne, 202.8-tonne and 131.4-tonne under three different loads, while the highest coal consumption is obtained in the winter solstice.Item Open Access Performance analysis of a novel combined solar trough and tower aided coal-fired power generation system(Elsevier, 2020-04-15) Liu, Hongtao; Zhai, Rongrong; Patchigolla, Kumar; Turner, Peter J.; Yang, YongpingSolar-aided coal-fired power generation systems have been extensively studied and exhibit several advantages in the utilisation of solar energy. The issue with the solar augmentation of coal-fired plants is the limitation of the potential solar contribution that is practical to achieve when considering boiler safety issues. This study proposes the combination of parabolic troughs and solar towers to collect solar energy, that is then introduced into the preheaters and boilers of coal-fired power plants. Under the same investment conditions, this combination of solar technologies can provide more solar exergy and reduce the practical constraints on the solar contribution. The paper shows that the potential for a 660MWe power plant, integrated with a combined solar field allows the highest solar exergy share of 8.51% to be reached. This enables an increased fuel saving of at least 1.58 and 4.24 g/kWh compared to other systems, that gives a minimum coal consumption of 253.17 and 255.83 g/kWh, respectively. The combined solar field provides a maximum available solar exergy of 69.43 MWth, which is 7.83%–11.88% higher than the alternative compared systems. The enhanced solar exergy contribution and cost-effectiveness can be observed in this novel system under different solar loads and cost conditions.