Browsing by Author "Highgate, D. J."
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Item Open Access Low-Temperature Thermal-Energy Storage and Transmission Systems Employing Hydrophilic Polymeric Materials(Cranfield University, 1997-04) Augood, P. C.; Newborough, M.; Highgate, D. J.The wide fluctuations that occur in the aggregate electrical demand of a generating utility are punitive with respect to total system efficiency. Demand side management techniques have been applied to reduce such fluctuations including the conversion of electrical energy to thermal energy during periods of low demand for use during peak demand periods. For thermal processes requiring energy above ambient temperature it is feasible to use sensible heat due to the existence of stable storage mediums and efficient methods of heating at the high temperatures required. However where energy is required below ambient temperatures, efficiency of cooling limits the use of sensible heat, hence latent heat storage has been adopted. Conventional cold storage systems use ice banks to store cooling energy at 0°C in order to capture the high latent heat of fusion of water. The rate of discharge for such stores is limited by thermal resistance in the store and the thermal capacity of secondary coolants (such as glycol solutions). This investigated the use of hydrophilic materials to overcome the limitations of current cold-storage technology. Such materials have the capacity to absorb and retain up to 95% by mass of water (or other aqueous solutions) regardless of how the materials is subdivided. Furthermore the thermal properties of the polymers in their hydrated state resemble those of the free hydration fluid, including any phase transitions. By supporting the hydrated materials in a non-freeing, non-aqueous fluid the resultant mixture provides a medium for cold storage that can be pumped and used at the point of load, and is not limited by the thermal resistance of an encapsulating material. Three aspects concerning the utilisation of hydrophilic materials for thermal engineering applications have been investigated; (i) the physical properties of the materials in their hydrated state, (ii) methods of fluidising material in a high density store, and (iii) the heat transfer properties of hydrophilic based slurries while undergoing phase transition. Material tests have shown that currently available hydrophilic materials have thermo- physical properties that depend principally upon the hydrating fluid, regardless of particle size, and are stable over long periods (>3years). Suitable hydration fluids can lower the temperature of the phase transition thus extending their potential as storage mediums beyond those of ice-based technologies. Novel materials, of very high water content (95%) have been produced and investigated. These appear to be very suitable for thermal storage because they increase the maximum achievable energy densities of a fluidised storage system and potentially reduce cost. A number of thermal storage devices to utilise hydrophilic based slurries have been designed and evaluated. The resultant devices has been shown to provide a means of taking hydrophilic materials to, and from, a packed bed and feeding them at a controlled rate into a fluid stream. The thermal charge/discharge rates of such a device are limited only by the choice of external heat exchange systems. An experimental apparatus has been designed to investigate the effects of phase change particles on the heat transfer properties of flowing mixtures. The results have shown that (i) at temperatures above the phase transition temperature the presence of the particles causes an increase in the measured heat transfer coefficient for concentrations above 10% by volume, (ii) there is a significant interaction of particles at the heat transfer surface, and (iii) that under high flow rate conditions, with phase change occurring, heat transfer coefficients are considerably enhanced (ie 80%) above those of the support fluid when used alone or with non-active particles. Further work is recommended to extend this study to produce an engineering prototype storage system for trial evaluation.Item Open Access Novel hydrophilic polymer couplant for application in ultrasonic non destructive testing(Cranfield University, 2001) Bourne, Simon James; Newborough, M.; Highgate, D. J.Ultrasonic Non Destructive Testing (NDT) is used to inspect materials and structures for defects. Water is commonly used in NDT as a couplant to improve ultrasonic transfer between an interrogating probe and test piece. Unfortunately, the presence of water can cause corrosion and/or degradation of the test piece material. The aim of this investigation was to evaluate hydrated cross-linked hydrophilic polymers as candidate solid contact ultrasonic couplant for use in the field of ultrasonic NDT. The fact that hydrophilic polymers can absorb and retain large quantities of water suggested that they might demonstrate the desirable ultrasonic properties of water without the risks associated with conventional water coupling. To test this, the ultrasonic properties of a range of hydrophilic polymers were assessed. Excellent results were achieved, attenuation as low as 0.36 and 0.71dB mm-1 at 5 and 1OMHz respectively being measured. Great potential for efficient coupling was established due to acoustic impedance in the region of 1.81VIN S M-3. A polymer dependant coupling pressure of less that 1kg CM-2 was required to achieve optimum coupling to a smooth steel block. Mechanical longevity, evaluated by life testing, showed that polymers of up to 70% equilibrium water content were best suited for dynamic testing applications. Temperature was shown to effect ultrasonic properties; a drop from 5 to -120C caused an increase in attenuation of 3dB mm-1 and velocity of 350m s-1. Pressure demonstrated no influence on attenuation but affected an increase in velocity of 44m s-1 per kg CM-2 . Further investigation into the unique ultrasonic properties of hydrophilic polymers showed that the water sorption process caused an increase in attenuation prior to saturation being reached. This was attributed to the absorption of sound during the polymer transformation from the glassy to rubbery condition observed during hydration. Dehydration from 100 to 37% saturation in a 60% equilibrium water content polymer caused an increase in attenuation of 1.8dB mm-1 at 5MHz. The research concluded with the design and development of a prototype wheel probe employing hydrophilic polymer as the tyre. Operation at 5MHz in pulse echo mode demonstrated results competitive to conventional immersion testing. An MMA-VP cross-linked hydrophilic polymer of approximately 60% equilibrium water content was found most suitable to this application. This thesis suggests that there is a clear role for hydrophilic polymers in ultrasonic NDT. The success of the wheel probe design developed as a result of this research has resulted in patent application in both the UK and USA.Item Open Access Refrigeration appliances : Performance enchancements via novel thermal-energy storage(Cranfield University, 1999-10) Lawson, Chukwuemeka Jonathan Adeolu; Newborough, M.; Highgate, D. J.In recent * years there has been increasing concern for the environmental impacts of economic and technological development. This (principally socio-political) con- cern has led to the well-known series of environmentall ,y motivated (global and local) conventions, agreements and legislation put forward in a bid to manage these environmental impacts, which in turn has led to research and commercial activ- ity on environmental issues. One of the major activities identified as adversely impacting the environment is the manner in which energy is currently harnessed, inter-converted and utilised. Cont/d.