Browsing by Author "Arafat, Hassan A."
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Item Open Access Polydopamine-coated graphene oxide nanosheets embedded in sulfonated poly (ether sulfone) hybrid UF membranes with superior antifouling properties for water treatment(Elsevier, 2021-11-11) Kumar, Mahendra; Sreedhar, Nurshaun; Thomas, Navya; Mavukkandy, Musthafa; Ismail, Roqaya A.; Aminabhavi, Tejraj M.; Arafat, Hassan A.A novel high-performance hybrid ultrafiltration (UF) membrane was fabricated by blending polydopamine-coated graphene oxide (PDGO) nanosheets with sulfonated poly(ether sulfone) (SPES) via phase inversion method and tested for the removal of natural organic matter (humic acid; HA) from aqueous solution. The PDGO nanosheets were synthesized via self-polymerization of dopamine with GO nanosheets in alkaline tris-buffer solution at room temperature for 24 h and were fully characterized. Hybrid SPES membranes were prepared by incorporating 1–10 wt% of PDGO, which were further characterized by Raman spectroscopy, surface zeta potential, and field emission scanning electron microscopy to confirm membrane stability without any defects even by adding up to 10 wt%, of PDGO nanosheets. The membranes demonstrated a significant increase in hydrophilicity, water flux, and retention rate for HA (RHA). For instance, water permeability with 5 wt% PDGO (M5) (680.7 L m−2 h−1 bar−1) was ca. 1.8-folds that of the pristine SPES membrane (380.8 L m−2 h−1 bar−1), while maintaining an HA rejection (RHA) of 91.7% for a 50 ppm HA feed solution. This was accompanied by a distinct increase in surface hydrophilicity of M5, which showed a water contact angle of 27.8°, well below that of pristine SPES membrane (59.1°). The hybrid UF membranes also demonstrated a significant reduction in HA adhesion onto the membrane surface along with a superior antifouling performance for the membrane containing 10 wt% PDGO, giving irreversible fouling ratio (Rir) of only 6.9% compared to 32.7% for the pristine membrane.Item Open Access Utilizing Buckingham Pi theorem and multiple regression analysis in scaling up direct contact membrane distillation processes(Elsevier, 2022-02-05) Khafajah, Heba; Ali, Mohamed I. Hassan; Thomas, Navya; Janajreh, Isam; Arafat, Hassan A.Predicting the performance of a full-scale direct contact membrane distillation (DCMD) module based on experimental lab-scale results is rather difficult, since the DCMD performance is dependent on many different process parameters. Hence, there is a need for a methodology to perform DCMD system up-scaling based on lab-scale experimental results. In this study, we devise an approach to scale up the performance of DCMD systems by using the Buckingham's Pi theorem to group the DCMD process parameters into eight relevant dimensionless groups. Experimental data obtained from literature at various module dimensions were used to evaluate the developed dimensionless groups. An experimentally validated computational fluid dynamics (CFD) model was also developed and used to extend the coverage of operational parameters beyond the available experimental data. Then, two empirical dimensionless correlations were created, using multiple nonlinear regression analysis, and then validated, to enable the prediction of flux and pressure drop in DCMD systems at any scale.