Dossi, EleftheriaAkhavan, JacquelineGaulter, Sally E.Williams, Richard G.Doe, William J.2021-01-192021-01-192018-01-16Dossi, E, Akhavan J, Gaulter SE, et al., (2018) Cross-linking of hydroxyl-terminated polyols with triethyleneglycol diglycidyl ether: an alternative to toxic isocyanates. Propellants, Explosives, Pyrotechnics, Volume 43, Issue 3, 2018, pp.241-2500721-3115https://doi.org/10.1002/prep.201700220http://dspace.lib.cranfield.ac.uk/handle/1826/16200Isocyanates are highly reactive and toxic substances with severe health effects. Certain diisocyanates are restricted under REACH – The European Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals. Triethyleneglycol diglycidyl ether (TEGDGE) was used as an alternative to toxic isocyanates for the cross-linking of hydroxyl-terminated pre-polymers at 70oC. The effect of three curing accelerators was determined while following the reaction kinetics by 1H-NMR spectroscopy and differential scanning calorimetry (DSC). Polybutadiene (Poly BD R45HT-LO) and acrylic ester (HyTemp 4454) successfully cross-linked in 7–10 days to produce thermally stable networks with low glass transition temperatures, as observed by DSC. Pre-aging the polybutadiene resin promoted cross-linking with TEGDGE. Four energetic compositions were then prepared using cyclotrimethylenetrinitramine (RDX) and pentaerythritoltetranitrate (PETN) as fillers, and polybutadiene (Poly BD R45HT-LO) and acrylic ester (HyTemp 4454) as binders. Both binders successfully cross-linked with TEGDGE in the presence of RDX and PETN, but only PETN was found to be chemically compatible with the cross-linked polymers. These results show that TEGDGE is suitable as a replacement for toxic isocyanates for the cross-linking of hydroxyl-terminated polyols.enAttribution-NonCommercial 4.0 InternationalPETNRDXcross-linked polymershydroxyl-terminatedToxic isocyanatesArticle