Browsing by Author "Guo, Yaofeng"

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    In-situ monitoring the structural pathway of a Ti-based alloy from metallic liquid to metallic glass
    (Elsevier, 2025-04-25) Georgarakis, Konstantinos; Stiehler, Martin E.; Hennet, Louis; Guo, Yaofeng; Antonowicz, Jerzy; Louzguine-Luzgin, Dmitri V.; Jolly, Mark R.; Andrieux, Jérôme; Vaughan, Gavin B. M.; Greer, A. Lindsay
    A metallic glass is formed when a molten metallic alloy is cooled rapidly enough that crystallisation is avoided. However, the way the atomic structure of the liquid converts to that of the glass is generally unknown. The main challenge is the sufficiently fast experimental acquisition of structural data in the undercooled liquid regime necessitated by the high cooling rates needed to avoid crystallisation. In the present study, using aerodynamic levitation, the Ni-free Ti-based alloy Ti40Zr10Cu34Pd14Sn2 was vitrified in-situ in a high-energy synchrotron X-ray beam while diffraction data were acquired during cooling from above the liquidus temperature Tliq to well below the glass-transition temperature Tg. The structure in the undercooled liquid regime shows an accelerated evolution. Both the local order in the short (SRO) and medium range (MRO) increases rapidly as the undercooled liquid approaches Tg, below which the amorphous structure “freezes”. Nevertheless, distinct differences between the evolution of SRO and MRO were observed. The structural rearrangements in the undercooled liquid are found to be correlated with a rapid increase in viscosity of the metallic liquid upon cooling. The new findings shed light on the evolution of the atomic structure of metallic liquids during vitrification and the structural origins of the sluggish kinetics that suppress nucleation and growth of crystalline phases.
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    Interaction between Fe66Cr10Nb5B19 metallic glass and aluminum during spark plasma sintering
    (Elsevier, 2020-08-28) Dudina, Dina V.; Bokhonov, Boris B.; Batraev, Igor S.; Amirastanov, Yusif N.; Ukhina, Arina V.; Kuchumova, Ivanna D.; Legan, Mikhail A.; Novoselov, Aleksey N.; Gerasimov, Konstantin B.; Bataev, Ivan A.; Georgarakis, Konstantinos; Koga, Guilherme Yuuki; Guo, Yaofeng; Botta, Walter José; Jorge, Alberto Moreira
    In the area of metal matrix composites, novel reinforcing options are currently being evaluated. Particles of amorphous alloys present an interesting possibility to reinforce soft metals. In the present work, the interaction between Fe66Cr10Nb5B19 metallic glass and aluminum during spark plasma sintering (SPS) was studied for the first time. In order to trace the phase and microstructural changes upon sintering, mixtures containing 20 vol% and 50 vol% of metallic glass were subjected to SPS at 500–570 °C. After SPS at 500 °C, no reaction layer between the metallic glass particles and aluminum was observed. After SPS at 570 °C, a reaction layer containing Fe2Al5 and FeAl3 formed around the Fe-based cores. The Vickers hardness of composites obtained from mixtures containing 20 vol% Fe66Cr10Nb5B19 at 540 °C was 75 HV and increased to 280 HV after sintering at 570 °C due to the formation of thicker reaction layers at the interface. The hardness of the composite sintered from the mixture containing 20 vol% Fe66Cr10Nb5B19 at 570 °C was between the values predicted by Reuss and Voigt models. Comparison of results of SPS of the powder mixtures with those of SPS of a pre-compacted pellet and electric current-free annealing suggests that local heating at the interface caused by interfacial resistance may be an important factor influencing the reaction advancement at the interface and the formation of Al-containing intermetallics